Dortmund Data Bank

Vapor-Liquid Equilibrium Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.

Vapor-Liquid Equilibrium Data Set 1304

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C2H4O2 60.053 64-19-7 Acetic acid
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Constant Value

Pressure 101.33 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]
391.25 0.00000 0.00000
379.95 0.03000 0.21510
374.85 0.03000 0.26420
374.45 0.08100 0.33800
368.85 0.11720 0.45150
368.55 0.12220 0.45680
361.95 0.18630 0.57850
354.55 0.28140 0.70610
347.55 0.40080 0.80580
343.65 0.50620 0.85720
343.05 0.52560 0.88020
340.95 0.61270 0.90880
338.05 0.75070 0.94280
334.35 1.00000 1.00000

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Conti J.J.; Othmer D.F.; Gilmont R.: Composition of Vapors from Boiling Binary Solutions. Systems Containing Formic Acid, Acetic Acid, Water and Chloroform. J.Chem.Eng.Data 5 (1960) 301-307


Vapor-Liquid Equilibrium Data Set 1892

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C2H4O2 60.053 64-19-7 Acetic acid
Search the DDB for all data of this mixture

Constant Value

Temperature 298.15 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]
2.1065 0.00000 0.00000
6.186 0.08507 0.52358
6.839 0.10677 0.58751
7.813 0.13385 0.65426
10.319 0.20873 0.77255
12.466 0.28163 0.82735
13.559 0.31364 0.84581
18.812 0.52590 0.92719
23.131 0.74635 0.96484
26.544 1.00000 1.00000

(P - pressure, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Campbell A.N.; Kartzmark E.M.; Gieskes J.M.T.M.: Vapor-Liquid Equilibria, Densities and Refractives in the System Acetic Acid-Chloroform-Water at 25°C. Can.J.Chem. 41 (1963) 407-429


Vapor-Liquid Equilibrium Data Set 8843

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C2H4O2 60.053 64-19-7 Acetic acid
Search the DDB for all data of this mixture

Constant Value

Pressure 101.33 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]
391.25 0.00000 0.00000
386.85 0.00709 0.06991
379.15 0.04739 0.22129
369.95 0.09944 0.43826
366.65 0.12046 0.50639
354.95 0.26299 0.70194
354.65 0.27508 0.69619
344.15 0.48079 0.85946
342.95 0.51094 0.87158
336.45 0.83401 0.96869
334.65 0.97642 0.99603
334.55 1.00000 1.00000

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Campbell A.N.; Gieskes J.M.T.M.: The Isobaric Boiling Points of the System Acetic Acid-Chloroform-Water at a Pressure of 760mmHg. Can.J.Chem. 42 (1964) 186-189

Diagrams

Vapor-Liquid Equilibrium of Chloroform+Acetic acid
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Vapor-Liquid Equilibrium of Chloroform+Acetic acid
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Vapor-Liquid Equilibrium of Chloroform+Acetic acid
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Vapor-Liquid Equilibrium of Chloroform+Acetic acid
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List of All References

Source
Conti J.J.; Othmer D.F.; Gilmont R.: Composition of Vapors from Boiling Binary Solutions. Systems Containing Formic Acid, Acetic Acid, Water and Chloroform. J.Chem.Eng.Data 5 (1960) 301-307
Campbell A.N.; Kartzmark E.M.; Gieskes J.M.T.M.: Vapor-Liquid Equilibria, Densities and Refractives in the System Acetic Acid-Chloroform-Water at 25°C. Can.J.Chem. 41 (1963) 407-429
Campbell A.N.; Gieskes J.M.T.M.: The Isobaric Boiling Points of the System Acetic Acid-Chloroform-Water at a Pressure of 760mmHg. Can.J.Chem. 42 (1964) 186-189

Vapor-Liquid Equilibrium Data Overview


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