Dortmund Data Bank

Excess Volume Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.

Excess Volume Data Set 8

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Constant Value

Temperature 298.150 K

Data Table

Excess Volume [cm3/mol] x1 [mol/mol]
-0.2520 0.10000
-0.3960 0.15149
-0.5000 0.19984
-0.6500 0.25000
-0.7410 0.30001
-0.8690 0.34997
-0.9620 0.39987
-1.0530 0.45001
-1.1110 0.49979
-1.1620 0.55000
-1.1950 0.59999
-1.1740 0.65018
-1.1380 0.69998
-1.0380 0.74998
-0.8980 0.79967
-0.8260 0.82004
-0.7480 0.83860
-0.6490 0.85994
-0.5520 0.87998
-0.4510 0.89930
-0.3440 0.91999
-0.2380 0.93994
-0.1360 0.96005
-0.0560 0.98002

Reference

Source
Uosaki Y.; Sogo K.; Kunumine T.; Moriyoshi T.: Excess molar volumes of (a cyclic amide + water) at 298.15 K and 308.15 K.. J.Chem.Thermodyn. 22 (1990) 257-262


Excess Volume Data Set 9

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Constant Value

Temperature 308.150 K

Data Table

Excess Volume [cm3/mol] x1 [mol/mol]
-0.1570 0.05000
-0.3100 0.10000
-0.4490 0.15001
-0.5750 0.20000
-0.6810 0.25003
-0.7910 0.30002
-0.8840 0.34993
-0.9790 0.40000
-1.0450 0.44996
-1.1020 0.49996
-1.1370 0.55003
-1.1490 0.59994
-1.1280 0.65003
-1.0800 0.70002
-0.9810 0.74999
-0.8410 0.79991
-0.7690 0.81994
-0.6920 0.83994
-0.6040 0.86001
-0.5110 0.87986
-0.4180 0.90000
-0.3210 0.91999
-0.2440 0.94005
-0.1330 0.95999
-0.0550 0.98001

Reference

Source
Uosaki Y.; Sogo K.; Kunumine T.; Moriyoshi T.: Excess molar volumes of (a cyclic amide + water) at 298.15 K and 308.15 K.. J.Chem.Thermodyn. 22 (1990) 257-262


Excess Volume Data Set 1049

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Constant Value

Temperature 298.150 K

Data Table

Excess Volume [cm3/mol] x1 [mol/mol]
-0.009232 0.00320
-0.019028 0.01450
-0.05962 0.03050
-0.2624 0.09490
-0.3579 0.14580
-0.3666 0.15040
-0.6808 0.26380
-0.8838 0.36480
-1.0466 0.44240
-1.0607 0.46140
-1.1588 0.54410
-1.1730 0.65750
-1.1716 0.66230
-1.0359 0.75280
-0.8079 0.82390
-0.6677 0.85740
-0.5981 0.87190
-0.31086 0.92710
-0.12164 0.96470
-0.017097 0.99250

Reference

Source
Wu Z.; Zeck S.; Knapp H.: Measurements of the Solubility of Carbon Dioxide, Ethylene and Methane in n-Methylpyrrolidone and in its Aqueous Solution. Ber.Bunsen-Ges.Phys.Chem. 89 (1985) 1009-1013

Diagrams

Excess Volume of Water+N-Methyl-2-pyrrolidone
See larger image

List of All References

Source
Uosaki Y.; Sogo K.; Kunumine T.; Moriyoshi T.: Excess molar volumes of (a cyclic amide + water) at 298.15 K and 308.15 K.. J.Chem.Thermodyn. 22 (1990) 257-262
Wu Z.; Zeck S.; Knapp H.: Measurements of the Solubility of Carbon Dioxide, Ethylene and Methane in n-Methylpyrrolidone and in its Aqueous Solution. Ber.Bunsen-Ges.Phys.Chem. 89 (1985) 1009-1013

Excess Volume Data Overview


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