Dortmund Data Bank

Excess Volume Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Excess Volume Data Set 875

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C4H10O 74.123 71-36-3 1-Butanol
Search the DDB for all data of this mixture

Constant Value

Temperature 298.150 K

Data Table

Excess Volume [cm3/mol] x1 [mol/mol]
0.0158 0.09463
0.0370 0.21703
0.0476 0.28588
0.0640 0.40219
0.0742 0.50118
0.0807 0.60081
0.0800 0.70054
0.0698 0.79863
0.0595 0.84896
0.0447 0.90074
0.0254 0.94995

Reference

Source
Ogawa H.; Murakami S.: Excess Volumes, Isentropic Compressions, and Isobaric Heat Capacities for Methanol Mixed with Other Alkanols at 25 °C. J.Solution Chem. 16 (1987) 315-326


Excess Volume Data Set 2319

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C4H10O 74.123 71-36-3 1-Butanol
Search the DDB for all data of this mixture

Constant Value

Temperature 298.150 K

Data Table

Excess Volume [cm3/mol] x1 [mol/mol]
0.0110 0.06210
0.0232 0.13380
0.0381 0.22570
0.0527 0.32140
0.0640 0.40640
0.0729 0.48660
0.0779 0.55370
0.0805 0.61160
0.0808 0.65790
0.0799 0.66750
0.0798 0.69500
0.0790 0.70030
0.0781 0.72610
0.0768 0.73500
0.0732 0.77130
0.0675 0.80900
0.0598 0.84720
0.0500 0.88460
0.0388 0.91760
0.0270 0.94740
0.0158 0.97150
0.0070 0.98760

Reference

Source
Pflug H.D.; Benson G.C.: Molar Excess Volumes of Binary n-Alcohol Systems at 25°C. Can.J.Chem. 46 (1968) 287-294


Excess Volume Data Set 9776

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C4H10O 74.123 71-36-3 1-Butanol
Search the DDB for all data of this mixture

Constant Value

Temperature 298.150 K

Data Table

Excess Volume [cm3/mol] x1 [mol/mol]
0.0140 0.10740
0.0250 0.19410
0.0340 0.27380
0.0460 0.34270
0.0530 0.37430
0.0630 0.49700
0.0670 0.64220
0.0660 0.68770
0.0630 0.72670
0.0600 0.75990
0.0490 0.80560
0.0460 0.83460
0.0280 0.89350
0.0150 0.92530
0.0070 0.96820

Reference

Source
Iglesias M.; Orge B.; Tojo J.: Refractive indices, densities and excess properties on mixing of the systems acetone + methanol + water and acetone + methanol + 1-butanol at 298.15 K. Fluid Phase Equilib. 126 (1996) 203-223

Diagrams

Excess Volume of 1-Butanol+Methanol
See larger image

List of All References

Source
Ogawa H.; Murakami S.: Excess Volumes, Isentropic Compressions, and Isobaric Heat Capacities for Methanol Mixed with Other Alkanols at 25 °C. J.Solution Chem. 16 (1987) 315-326
Pflug H.D.; Benson G.C.: Molar Excess Volumes of Binary n-Alcohol Systems at 25°C. Can.J.Chem. 46 (1968) 287-294
Iglesias M.; Orge B.; Tojo J.: Refractive indices, densities and excess properties on mixing of the systems acetone + methanol + water and acetone + methanol + 1-butanol at 298.15 K. Fluid Phase Equilib. 126 (1996) 203-223

Excess Volume Data Overview


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