Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 7115

Components

No. Formula Molar Mass CAS Registry Number Name
1 C8H10 106.167 106-42-3 p-Xylene
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.200 K

Data Table

hE [J/mol] x1 [mol/mol]
-3.600 0.09000
-8.400 0.13490
-2.600 0.29940
14.100 0.43900
18.400 0.46980
33.400 0.49220
36.000 0.55020
53.600 0.61990
69.700 0.80130
77.700 0.82110

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hammerl I.; Vogel A.; Bittrich H.-J.: Exzeßenthalpien von N-Methylpyrrolidon- (NMP) und N-Methylcaprolactam- (NMC) Systemen. Z.Phys.Chem.(Leipzig) 271 (1990) 477-482


Enthalpy of Mixing Data Set 7116

Components

No. Formula Molar Mass CAS Registry Number Name
1 C8H10 106.167 106-42-3 p-Xylene
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 313.200 K

Data Table

hE [J/mol] x1 [mol/mol]
24.200 0.12970
56.000 0.23340
89.100 0.35400
98.300 0.42410
109.900 0.44380
150.000 0.58060
191.100 0.76630
180.600 0.80710
128.600 0.90160

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hammerl I.; Vogel A.; Bittrich H.-J.: Exzeßenthalpien von N-Methylpyrrolidon- (NMP) und N-Methylcaprolactam- (NMC) Systemen. Z.Phys.Chem.(Leipzig) 271 (1990) 477-482


Enthalpy of Mixing Data Set 7684

Components

No. Formula Molar Mass CAS Registry Number Name
1 C8H10 106.167 106-42-3 p-Xylene
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 363.150 K
Pressure 7.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
20.517 0.08000
20.384 0.08000
44.051 0.16370
44.154 0.16370
71.109 0.25120
98.440 0.34290
125.702 0.43910
152.734 0.54010
172.184 0.64620
174.951 0.75790
162.248 0.81600
152.612 0.84570
137.346 0.87570
116.064 0.90610
87.836 0.93700
49.704 0.96830

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Gmehling J.; Meents B.: Excess Enthalpies of 1-Methyl-2-pyrrolidinone + Cyclohexane, + Benzene, + Toluene, or + 1,4-Dimethylbenzene. Int.Data Series Sel.Data Mixtures Ser. A 1992 (1992) 210-213

Diagrams

Excess Enthalpies of p-Xylene+N-Methyl-2-pyrrolidone
See larger image

List of All References

Source
Hammerl I.; Vogel A.; Bittrich H.-J.: Exzeßenthalpien von N-Methylpyrrolidon- (NMP) und N-Methylcaprolactam- (NMC) Systemen. Z.Phys.Chem.(Leipzig) 271 (1990) 477-482
Gmehling J.; Meents B.: Excess Enthalpies of 1-Methyl-2-pyrrolidinone + Cyclohexane, + Benzene, + Toluene, or + 1,4-Dimethylbenzene. Int.Data Series Sel.Data Mixtures Ser. A 1992 (1992) 210-213

Excess Enthalpy Data Overview


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