Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 3740

Components

No. Formula Molar Mass CAS Registry Number Name
1 C8H10 106.167 106-42-3 p-Xylene
2 C8H10 106.167 108-38-3 m-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-0.879 0.03510
-1.424 0.05170
-2.470 0.09830
-3.140 0.12690
-3.936 0.16660
-4.605 0.20280
-5.317 0.24650
-5.820 0.28560
-6.238 0.32090
-6.531 0.35280
-6.824 0.39550
-6.950 0.42090
-7.076 0.45530
-7.118 0.47100
-7.159 0.48100
-7.118 0.49920
-7.076 0.51350
-7.034 0.53920
-6.866 0.57980
-6.699 0.61290
-6.531 0.63450
-6.322 0.65780
-5.987 0.69160
-5.401 0.73910
-4.940 0.77090
-4.354 0.80550
-3.391 0.85670
-2.512 0.89970
-1.884 0.93080
-0.921 0.96420

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Holt D.L.; Smith B.D.: Measurement of Excess Enthalpies with Tronac Titration Calorimeter. Data for Some C8 Aromatic Binaries. J.Chem.Eng.Data 19 (1974) 129-133


Enthalpy of Mixing Data Set 3741

Components

No. Formula Molar Mass CAS Registry Number Name
1 C8H10 106.167 106-42-3 p-Xylene
2 C8H10 106.167 108-38-3 m-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-1.300 0.03980
-1.200 0.04420
-2.600 0.08690
-2.800 0.10240
-4.000 0.15360
-4.400 0.18280
-5.700 0.23960
-5.800 0.25990
-6.600 0.30950
-6.800 0.33670
-7.200 0.38360
-7.500 0.40960
-7.700 0.43250
-7.500 0.44820
-7.600 0.44990
-7.600 0.48730
-7.700 0.50280
-7.500 0.54510
-7.500 0.56350
-7.300 0.60840
-6.800 0.62860
-6.600 0.67620
-5.900 0.69760
-5.600 0.74890
-5.700 0.76990
-4.100 0.83420
-4.000 0.84570
-2.600 0.90690
-2.600 0.91660
-1.000 0.96210
-1.100 0.96660

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Lam V.T.; Murakami S.; Benson G.C.: III. Excess Enthalpies and Volumes of Isomeric Xylene Mixtures at 25°C. J.Chem.Thermodyn. 2 (1970) 17-25


Enthalpy of Mixing Data Set 12157

Components

No. Formula Molar Mass CAS Registry Number Name
1 C8H10 106.167 106-42-3 p-Xylene
2 C8H10 106.167 108-38-3 m-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 288.650 K

Data Table

hE [J/mol] x1 [mol/mol]
-1.340 0.24600
-10.886 0.70800

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Kremann R.; Meingast R.; Gugl F.: II.Mitteilung: Die Volumänderungen und Wärmeerscheinungen bei Bildung binärer Gemische. Monatsh.Chemie u.verw.Teil.and.Wiss. 35 (1914) 1235-1322

Diagrams

Excess Enthalpies of m-Xylene+p-Xylene
See larger image

List of All References

Source
Holt D.L.; Smith B.D.: Measurement of Excess Enthalpies with Tronac Titration Calorimeter. Data for Some C8 Aromatic Binaries. J.Chem.Eng.Data 19 (1974) 129-133
Lam V.T.; Murakami S.; Benson G.C.: III. Excess Enthalpies and Volumes of Isomeric Xylene Mixtures at 25°C. J.Chem.Thermodyn. 2 (1970) 17-25
Kremann R.; Meingast R.; Gugl F.: II.Mitteilung: Die Volumänderungen und Wärmeerscheinungen bei Bildung binärer Gemische. Monatsh.Chemie u.verw.Teil.and.Wiss. 35 (1914) 1235-1322

Excess Enthalpy Data Overview


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