Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 21763

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 H2O 18.015 7732-18-5 Water
3 C4H8O2S 120.172 126-33-0 Sulfolane
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 75.000 bar

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
-281.500 0.06830 0.17840
-557.000 0.13290 0.16600
-787.200 0.19410 0.15430
-970.600 0.25220 0.14320
-1159.700 0.30740 0.13260
-1311.600 0.35980 0.12260
-1418.500 0.40980 0.11300
-1543.100 0.45750 0.10390
-1646.800 0.50290 0.09520
-1625.400 0.54640 0.08690
-1538.000 0.58790 0.07890
-1422.000 0.62770 0.07130
-1307.100 0.66590 0.06400
-1202.300 0.70250 0.05700
-1079.000 0.73760 0.05020
-982.500 0.77130 0.04380
-883.100 0.80370 0.03760
-785.300 0.83500 0.03160
-683.200 0.86500 0.02590
-598.800 0.89400 0.02030
-520.900 0.92190 0.01500
-395.500 0.94880 0.00980
-275.300 0.97490 0.00480

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hauser R.A.; Zhao J.P.; Tremaine P.R.; Mather A.E.: Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa. J.Chem.Thermodyn. 28 (1996) 1303-1317


Enthalpy of Mixing Data Set 21764

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 H2O 18.015 7732-18-5 Water
3 C4H8O2S 120.172 126-33-0 Sulfolane
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 100.000 bar

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
-243.100 0.06990 0.17810
-446.500 0.13580 0.16550
-639.900 0.19800 0.15360
-805.100 0.25690 0.14230
-941.000 0.31260 0.13160
-1059.100 0.36550 0.12150
-1155.800 0.41580 0.11190
-1231.000 0.46360 0.10270
-1286.400 0.50910 0.09400
-1311.500 0.55250 0.08570
-1261.100 0.59390 0.07780
-1160.600 0.63350 0.07020
-1052.100 0.67130 0.06290
-965.800 0.70760 0.05600
-864.800 0.74230 0.04930
-776.500 0.77560 0.04300
-680.500 0.80760 0.03680
-620.900 0.83830 0.03100
-542.200 0.86790 0.02530
-459.400 0.89630 0.01990
-388.600 0.92370 0.01460
-295.100 0.95000 0.00960
-162.300 0.97550 0.00470

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hauser R.A.; Zhao J.P.; Tremaine P.R.; Mather A.E.: Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa. J.Chem.Thermodyn. 28 (1996) 1303-1317


Enthalpy of Mixing Data Set 21765

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 H2O 18.015 7732-18-5 Water
3 C4H8O2S 120.172 126-33-0 Sulfolane
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 125.000 bar

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
-218.100 0.06830 0.17840
-419.500 0.13290 0.16600
-591.900 0.19410 0.15430
-745.000 0.25220 0.14320
-870.900 0.30740 0.13260
-984.800 0.35980 0.12260
-1071.100 0.40980 0.11300
-1123.200 0.45750 0.10390
-1159.600 0.45750 0.10390
-1179.600 0.54640 0.08690
-1212.600 0.58800 0.07890
-1133.400 0.62770 0.07130
-1034.800 0.66590 0.06400
-925.800 0.70250 0.05700
-852.800 0.73760 0.05020
-763.800 0.77130 0.04380
-678.100 0.80370 0.03760
-619.300 0.83500 0.03160
-538.600 0.86500 0.02590
-468.400 0.89400 0.02030
-391.600 0.92190 0.01500
-298.500 0.94890 0.00980
-183.200 0.97490 0.00480

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hauser R.A.; Zhao J.P.; Tremaine P.R.; Mather A.E.: Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa. J.Chem.Thermodyn. 28 (1996) 1303-1317

List of All References

Source
Hauser R.A.; Zhao J.P.; Tremaine P.R.; Mather A.E.: Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa. J.Chem.Thermodyn. 28 (1996) 1303-1317

Excess Enthalpy Data Overview


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