Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 8897

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4 16.043 74-82-8 Methane
2 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 373.200 K
Pressure 1.010 bar

Data Table

hE [J/mol] x1 [mol/mol]
51.500 0.46500
52.300 0.48600
52.500 0.50200
52.800 0.50900
51.700 0.51500
52.600 0.53300
52.100 0.56200
50.300 0.56700
51.900 0.58000

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Smith G.; Sellars A.; Yerlett T.K.; Wormald C.J.: The Excess Enthalpy of (Water + Hydrogen) Vapour and (Water + Methane) Vapour. J.Chem.Thermodyn. 15 (1983) 29-35


Enthalpy of Mixing Data Set 8898

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4 16.043 74-82-8 Methane
2 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 383.200 K
Pressure 1.010 bar

Data Table

hE [J/mol] x1 [mol/mol]
39.700 0.30400
44.500 0.39200
46.800 0.42900
46.900 0.47500
48.000 0.50600
47.000 0.52100
47.200 0.54200
45.200 0.59300
43.400 0.62700
42.900 0.65000

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Smith G.; Sellars A.; Yerlett T.K.; Wormald C.J.: The Excess Enthalpy of (Water + Hydrogen) Vapour and (Water + Methane) Vapour. J.Chem.Thermodyn. 15 (1983) 29-35


Enthalpy of Mixing Data Set 8899

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4 16.043 74-82-8 Methane
2 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 393.200 K
Pressure 1.010 bar

Data Table

hE [J/mol] x1 [mol/mol]
35.500 0.32900
35.600 0.33000
37.600 0.36900
34.600 0.37200
42.700 0.39300
36.000 0.40800
41.700 0.44800
40.700 0.45200
39.600 0.47200
41.300 0.47300
40.900 0.48100
38.300 0.50900
37.800 0.52500
42.900 0.52900
40.500 0.53300
40.300 0.53400
39.700 0.55600
39.300 0.58100
39.200 0.60500
37.400 0.62700

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Smith G.; Sellars A.; Yerlett T.K.; Wormald C.J.: The Excess Enthalpy of (Water + Hydrogen) Vapour and (Water + Methane) Vapour. J.Chem.Thermodyn. 15 (1983) 29-35

Diagrams

Excess Enthalpies of Water+Methane
See larger image

List of All References

Source
Smith G.; Sellars A.; Yerlett T.K.; Wormald C.J.: The Excess Enthalpy of (Water + Hydrogen) Vapour and (Water + Methane) Vapour. J.Chem.Thermodyn. 15 (1983) 29-35

Excess Enthalpy Data Overview


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