Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 8027

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 548.200 K
Pressure 50.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
638.000 0.29900
715.000 0.40300
712.000 0.50300
661.000 0.60000
558.000 0.70200

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Wormald C.J.; Lancaster N.M.; Sellars A.J.: The Excess Molar Enthalpies of {xH2O + (1-x)CO}(g) and {xH2O + (1-x)CO2}(g) at High Temperatures and Pressures. J.Chem.Thermodyn. 18 (1986) 135-147


Enthalpy of Mixing Data Set 8028

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 598.200 K
Pressure 50.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
370.000 0.29800
415.000 0.39400
429.000 0.50000
406.000 0.59600
350.000 0.70200

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Wormald C.J.; Lancaster N.M.; Sellars A.J.: The Excess Molar Enthalpies of {xH2O + (1-x)CO}(g) and {xH2O + (1-x)CO2}(g) at High Temperatures and Pressures. J.Chem.Thermodyn. 18 (1986) 135-147


Enthalpy of Mixing Data Set 8029

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 648.200 K
Pressure 50.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
260.000 0.30300
295.000 0.40100
308.000 0.49700
292.000 0.59700
251.000 0.69800

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Wormald C.J.; Lancaster N.M.; Sellars A.J.: The Excess Molar Enthalpies of {xH2O + (1-x)CO}(g) and {xH2O + (1-x)CO2}(g) at High Temperatures and Pressures. J.Chem.Thermodyn. 18 (1986) 135-147

Diagrams

Excess Enthalpies of Water+Carbon dioxide
See larger image

List of All References

Source
Wormald C.J.; Lancaster N.M.; Sellars A.J.: The Excess Molar Enthalpies of {xH2O + (1-x)CO}(g) and {xH2O + (1-x)CO2}(g) at High Temperatures and Pressures. J.Chem.Thermodyn. 18 (1986) 135-147

Excess Enthalpy Data Overview


© DDBST GmbH