Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 12513

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 75.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
-554.600 0.17900
-933.300 0.32900
-1234.700 0.45600
-1472.900 0.56600
-1591.400 0.66200
-1613.900 0.70500
-1605.200 0.74600
-1482.000 0.82000
-1262.100 0.88600
-856.700 0.94600

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hauser R.A.; Zhao J.P.; Tremaine P.R.; Mather A.E.: Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa. J.Chem.Thermodyn. 28 (1996) 1303-1317


Enthalpy of Mixing Data Set 12514

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 106.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
-429.800 0.18300
-791.500 0.33400
-1073.500 0.46200
-1335.600 0.66700
-1334.400 0.71000
-1276.700 0.75000
-1149.900 0.82300
-919.100 0.88900
-306.400 0.97400

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hauser R.A.; Zhao J.P.; Tremaine P.R.; Mather A.E.: Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa. J.Chem.Thermodyn. 28 (1996) 1303-1317


Enthalpy of Mixing Data Set 12515

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 126.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
-430.200 0.18500
-738.000 0.33700
-1002.800 0.46500
-1170.000 0.57500
-1244.400 0.67000
-1185.800 0.75200
-1038.600 0.82500
-825.700 0.89000
-498.800 0.94700

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hauser R.A.; Zhao J.P.; Tremaine P.R.; Mather A.E.: Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa. J.Chem.Thermodyn. 28 (1996) 1303-1317

Diagrams

Excess Enthalpies of N-Methyl-2-pyrrolidone+Carbon dioxide
See larger image

List of All References

Source
Hauser R.A.; Zhao J.P.; Tremaine P.R.; Mather A.E.: Excess molar enthalpies of six (carbon dioxide + a polar solvent) mixtures at the temperatures 298.15 K and 308.15 K and pressures from 7.5 MPa to 12.6 MPa. J.Chem.Thermodyn. 28 (1996) 1303-1317

Excess Enthalpy Data Overview


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