Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 804

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C8H10 106.167 106-42-3 p-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 1.700 bar

Data Table

hE [J/mol] x1 [mol/mol]
482.900 0.05740
637.700 0.11350
682.900 0.15300
689.400 0.15810
717.100 0.19260
717.700 0.19700
736.000 0.22530
743.300 0.23940
744.400 0.25640
747.900 0.28600
745.800 0.28670
744.400 0.29140
747.500 0.31420
742.300 0.34370
742.300 0.34810
735.900 0.36450
721.600 0.39810
716.000 0.42910
684.400 0.47850
686.500 0.48660
674.200 0.50370
656.900 0.52820
650.600 0.53810
628.400 0.56310
629.400 0.56320
626.500 0.56360
613.100 0.58450
576.600 0.62650
531.700 0.66330
532.500 0.66770
431.400 0.74370
433.100 0.75080
354.200 0.81100
342.200 0.81880
263.600 0.86980
250.300 0.87550
221.400 0.89310
174.800 0.91820
162.400 0.92340
86.500 0.96280
79.800 0.96440

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Christensen J.J.; Rossiter B.E.; O'Neill T.K.; Hanks R.W.: The Excess Enthalpies of Six p-Xylene + Alcohol Mixtures at 298.15 K. J.Chem.Thermodyn. 10 (1978) 829-833


Enthalpy of Mixing Data Set 805

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C8H10 106.167 106-42-3 p-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
433.100 0.04620
587.300 0.09910
671.900 0.16010
710.600 0.22280
723.500 0.27970
714.200 0.36710
665.800 0.48260
574.700 0.60690
508.000 0.67560
465.800 0.71860
430.600 0.74340
414.300 0.76050
356.700 0.80300
286.500 0.84980
213.700 0.89380
126.100 0.94130
46.400 0.97960

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Nagata I.; Ogasawara Y.: Prediction of Ternary Excess Enthalpies from Binary Data.. Thermochim.Acta 52 (1982) 155-168


Enthalpy of Mixing Data Set 7177

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C8H10 106.167 106-42-3 p-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.200 K

Data Table

hE [J/mol] x1 [mol/mol]
520.500 0.08640
617.400 0.12460
689.600 0.18260
715.000 0.25700
720.800 0.28580
715.000 0.32610
709.400 0.34810
705.300 0.39420
680.500 0.43840
615.700 0.56320
526.800 0.65810
465.900 0.70660
376.100 0.78140
227.200 0.88260
139.500 0.93200

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Letcher T.M.; Prasad A.K.; Schoonbaert F.E.Z.; Mercer-Chalmers J.: Excess enthalpies of (a xylene + an alkanol) at 298.2 K. J.Chem.Thermodyn. 22 (1990) 765-770

Diagrams

Excess Enthalpies of Methanol+p-Xylene
See larger image

List of All References

Source
Christensen J.J.; Rossiter B.E.; O'Neill T.K.; Hanks R.W.: The Excess Enthalpies of Six p-Xylene + Alcohol Mixtures at 298.15 K. J.Chem.Thermodyn. 10 (1978) 829-833
Nagata I.; Ogasawara Y.: Prediction of Ternary Excess Enthalpies from Binary Data.. Thermochim.Acta 52 (1982) 155-168
Letcher T.M.; Prasad A.K.; Schoonbaert F.E.Z.; Mercer-Chalmers J.: Excess enthalpies of (a xylene + an alkanol) at 298.2 K. J.Chem.Thermodyn. 22 (1990) 765-770

Excess Enthalpy Data Overview


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