Dortmund Data Bank
Excess Enthalpy Data
The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.
Enthalpy of Mixing Data Set 815
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 2 |
H2O |
18.015 |
7732-18-5 |
Water |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -481.200 |
0.07800 |
| -663.500 |
0.12750 |
| -835.800 |
0.20400 |
| -881.600 |
0.27300 |
| -851.700 |
0.42350 |
| -843.100 |
0.45200 |
| -808.400 |
0.51100 |
| -782.400 |
0.52700 |
| -728.800 |
0.58750 |
| -629.500 |
0.68700 |
| -468.000 |
0.79550 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Abello L.: Enthalpies d'excès des systèmes binaires constitués d'hydrocarbures benzéniques et du chloroforme ou du méthylchloroforme. J.Chim.Phys.Phys.-Chim.Biol. 70 (1973) 1355-1359 |
Enthalpy of Mixing Data Set 816
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 2 |
H2O |
18.015 |
7732-18-5 |
Water |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -256.232 |
0.90400 |
| -221.900 |
0.92000 |
| -192.593 |
0.93200 |
| -183.382 |
0.93600 |
| -115.556 |
0.95900 |
| -75.362 |
0.97500 |
| -51.916 |
0.98300 |
| -23.153 |
0.99300 |
| -14.277 |
0.99600 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Belousov V.P.; Panov M.Yu.: XI. Lösungsenthalpie des Wassers in den Alkoholen. Vestn.Leningr.Univ.Fiz.Khim. 10 (1976) 149-150 |
Enthalpy of Mixing Data Set 817
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 2 |
H2O |
18.015 |
7732-18-5 |
Water |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -200.003 |
0.02920 |
| -499.904 |
0.08310 |
| -584.059 |
0.10290 |
| -607.923 |
0.10910 |
| -784.188 |
0.17250 |
| -830.661 |
0.20450 |
| -888.857 |
0.29490 |
| -886.345 |
0.32220 |
| -869.179 |
0.38640 |
| -819.357 |
0.47860 |
| -722.223 |
0.59780 |
| -637.649 |
0.67850 |
| -516.232 |
0.76840 |
| -351.272 |
0.86140 |
| -136.699 |
0.95280 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Benjamin L.; Benson G.C.: A Deuterium Isotope Effect on the Excess Enthalpy of Methanol Water Solutions. J.Phys.Chem. 67 (1963) 858-861 |
Diagrams
List of All References
| Source |
| Benjamin L.; Benson G.C.: A Deuterium Isotope Effect on the Excess Enthalpy of Methanol Water Solutions. J.Phys.Chem. 67 (1963) 858-861 |
| Abello L.: Enthalpies d'excès des systèmes binaires constitués d'hydrocarbures benzéniques et du chloroforme ou du méthylchloroforme. J.Chim.Phys.Phys.-Chim.Biol. 70 (1973) 1355-1359 |
| Belousov V.P.; Panov M.Yu.: XI. Lösungsenthalpie des Wassers in den Alkoholen. Vestn.Leningr.Univ.Fiz.Khim. 10 (1976) 149-150 |
Excess Enthalpy Data Overview
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