Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 11964

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4 16.043 74-82-8 Methane
2 CH4O 32.042 67-56-1 Methanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 255.400 K
Pressure 138.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
0.000 0.00880
-7.000 0.01750
-22.000 0.03230
-29.000 0.04260
-47.000 0.05280
-56.000 0.06250
-70.000 0.08170
-79.000 0.09100
-91.000 0.10030
-110.000 0.11770
-117.000 0.13470
-121.000 0.15140
-112.000 0.21060
-110.000 0.23790
-99.000 0.30780
-85.000 0.40080
-72.000 0.50090
-54.000 0.60080
-40.000 0.70070
-26.000 0.80060
-12.000 0.90030
-4.000 0.94750

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Oscarson J.L.; Coxam J.Y.; Gillespie S.E.; Izatt R.M.: Excess enthalpies of mixing methane with methanol, n-heptane, toluene and methylcyclohexane at 255.4 and 310.9 K and 13.8 MPa. Fluid Phase Equilib. 114 (1996) 161-174


Enthalpy of Mixing Data Set 11965

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4 16.043 74-82-8 Methane
2 CH4O 32.042 67-56-1 Methanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 310.900 K
Pressure 138.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
-5.000 0.00620
-9.000 0.00870
-21.000 0.02300
-34.000 0.03190
-30.000 0.03190
-27.000 0.03190
-64.000 0.06160
-72.000 0.06190
-91.000 0.08050
-101.000 0.08960
-101.000 0.09000
-96.000 0.09000
-97.000 0.11480
-96.000 0.11550
-106.000 0.11550
-110.000 0.11600
-109.000 0.11650
-115.000 0.12730
-105.000 0.14090
-115.000 0.14150
-102.000 0.14150
-103.000 0.14160
-99.000 0.16520
-93.000 0.18750
-93.000 0.18760
-89.000 0.20870
-85.000 0.22890
-82.000 0.22890
-79.000 0.24800
-75.000 0.26620

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Oscarson J.L.; Coxam J.Y.; Gillespie S.E.; Izatt R.M.: Excess enthalpies of mixing methane with methanol, n-heptane, toluene and methylcyclohexane at 255.4 and 310.9 K and 13.8 MPa. Fluid Phase Equilib. 114 (1996) 161-174

Diagrams

Excess Enthalpies of Methanol+Methane
See larger image

List of All References

Source
Oscarson J.L.; Coxam J.Y.; Gillespie S.E.; Izatt R.M.: Excess enthalpies of mixing methane with methanol, n-heptane, toluene and methylcyclohexane at 255.4 and 310.9 K and 13.8 MPa. Fluid Phase Equilib. 114 (1996) 161-174

Excess Enthalpy Data Overview


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