Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 7473

Components

No. Formula Molar Mass CAS Registry Number Name
1 N2 28.013 7727-37-9 Nitrogen
2 CH4 16.043 74-82-8 Methane
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Miscibility gap: No

Constant Value

Temperature 91.500 K

Data Table

hE [J/mol] x1 [mol/mol]
60.800 0.11700
109.900 0.24700
136.900 0.41100
139.800 0.47900
136.700 0.51400
106.800 0.71400

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
McClure D.W.; Lewis K.L.; Miller R.C.; Staveley L.A.K.: Excess Enthalpies and Gibbs Free Energies for Nitrogen + Methane at Temperatures Below the Critical Point of Nitrogen. J.Chem.Thermodyn. 8 (1976) 785-792


Enthalpy of Mixing Data Set 7474

Components

No. Formula Molar Mass CAS Registry Number Name
1 N2 28.013 7727-37-9 Nitrogen
2 CH4 16.043 74-82-8 Methane
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 105.000 K

Data Table

hE [J/mol] x1 [mol/mol]
96.900 0.28600
105.600 0.37800
109.000 0.42000
105.300 0.48600
101.200 0.56700
86.200 0.66300

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
McClure D.W.; Lewis K.L.; Miller R.C.; Staveley L.A.K.: Excess Enthalpies and Gibbs Free Energies for Nitrogen + Methane at Temperatures Below the Critical Point of Nitrogen. J.Chem.Thermodyn. 8 (1976) 785-792


Enthalpy of Mixing Data Set 8651

Components

No. Formula Molar Mass CAS Registry Number Name
1 N2 28.013 7727-37-9 Nitrogen
2 CH4 16.043 74-82-8 Methane
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.000 K
Pressure 21.300 bar

Data Table

hE [J/mol] x1 [mol/mol]
13.000 0.24000
17.000 0.36900
17.000 0.45700
17.000 0.53400
15.000 0.62500

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Wormald C.J.; Lewis K.L.; Mosedale S.: The Excess Enthalpies of Hydrogen + Methane, Hydrogen + Nitrogen, Methane + Nitrogen, Methane + Argon, and Nitrogen + Argon at 298 and 201 K at Pressures up to 10.2 MPa. J.Chem.Thermodyn. 9 (1977) 27-42

Diagrams

Excess Enthalpies of Methane+Nitrogen
See larger image

List of All References

Source
Wormald C.J.; Lewis K.L.; Mosedale S.: The Excess Enthalpies of Hydrogen + Methane, Hydrogen + Nitrogen, Methane + Nitrogen, Methane + Argon, and Nitrogen + Argon at 298 and 201 K at Pressures up to 10.2 MPa. J.Chem.Thermodyn. 9 (1977) 27-42
McClure D.W.; Lewis K.L.; Miller R.C.; Staveley L.A.K.: Excess Enthalpies and Gibbs Free Energies for Nitrogen + Methane at Temperatures Below the Critical Point of Nitrogen. J.Chem.Thermodyn. 8 (1976) 785-792

Excess Enthalpy Data Overview


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