Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 9134

Components

No. Formula Molar Mass CAS Registry Number Name
1 C6H14 86.177 110-54-3 Hexane
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
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Miscibility gap: No

Constant Value

Temperature 363.150 K
Pressure 8.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
266.000 0.03730
509.800 0.07570
739.800 0.11510
939.300 0.15560
1270.000 0.24010
1518.000 0.32950
1663.000 0.42430
1668.000 0.42430
1721.000 0.52510
1657.000 0.63230
1588.000 0.68860
1460.000 0.74670
1281.000 0.80680
1017.000 0.86900
1017.000 0.86900
624.800 0.93340
353.700 0.96640

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Fischer K.; Gmehling J.: Vapor-liquid equilibria, activity coefficients at infinite dilution and heats of mixing for mixtures of N-methyl pyrrolidone-2 with C5 or C6 hydrocarbons and for hydrocarbon mixtures. Fluid Phase Equilib. 119 (1996) 113-130


Enthalpy of Mixing Data Set 10727

Components

No. Formula Molar Mass CAS Registry Number Name
1 C6H14 86.177 110-54-3 Hexane
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
114.000 0.01500
131.000 0.01740
133.000 0.01780
149.000 0.01950
161.000 0.02110
220.000 0.03010

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Kedrina N.N.; Semenov L.V.; Gaile A.A.; Kaifadzhyan E.A.: Mischungsenthalpie der Kohlenwasserstoffe C5 und C6 mit polaren Lösungsmitteln. Oniitekhim (1983) 1-13

Diagrams

Excess Enthalpies of Hexane+N-Methyl-2-pyrrolidone
See larger image

List of All References

Source
Fischer K.; Gmehling J.: Vapor-liquid equilibria, activity coefficients at infinite dilution and heats of mixing for mixtures of N-methyl pyrrolidone-2 with C5 or C6 hydrocarbons and for hydrocarbon mixtures. Fluid Phase Equilib. 119 (1996) 113-130
Kedrina N.N.; Semenov L.V.; Gaile A.A.; Kaifadzhyan E.A.: Mischungsenthalpie der Kohlenwasserstoffe C5 und C6 mit polaren Lösungsmitteln. Oniitekhim (1983) 1-13

Excess Enthalpy Data Overview


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