Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 1610

Components

No. Formula Molar Mass CAS Registry Number Name
1 C6H14 86.177 110-54-3 Hexane
2 C3H8O 60.096 67-63-0 2-Propanol
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Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
211.433 0.12420
404.026 0.19950
777.907 0.45470
799.679 0.59150
817.682 0.69480
754.042 0.77300
558.938 0.86680

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Murakami S.; Amaya K.; Fujishiro R.: The Energy of Hydrogen Bonding between Alcohol and Ketone Molecules. Bull.Chem.Soc.Japan 37 (1964) 1776-1780


Enthalpy of Mixing Data Set 6166

Components

No. Formula Molar Mass CAS Registry Number Name
1 C6H14 86.177 110-54-3 Hexane
2 C3H8O 60.096 67-63-0 2-Propanol
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Miscibility gap: No

Constant Value

Temperature 333.150 K

Data Table

hE [J/mol] x1 [mol/mol]
29.930 0.00660
45.270 0.01000
60.310 0.01330
67.110 0.01470

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118


Enthalpy of Mixing Data Set 11678

Components

No. Formula Molar Mass CAS Registry Number Name
1 C6H14 86.177 110-54-3 Hexane
2 C3H8O 60.096 67-63-0 2-Propanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 293.150 K

Data Table

hE [J/mol] x1 [mol/mol]
591.344 0.32580
728.336 0.52800
729.717 0.67050
515.102 0.88170
112.164 0.99488
42.831 0.99821
22.358 0.99906

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Pahlke H.: Über Mischungswärmen organischer Substanzen. Thesis (1935)

Diagrams

Excess Enthalpies of Hexane+2-Propanol
See larger image

List of All References

Source
Murakami S.; Amaya K.; Fujishiro R.: The Energy of Hydrogen Bonding between Alcohol and Ketone Molecules. Bull.Chem.Soc.Japan 37 (1964) 1776-1780
Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118
Pahlke H.: Über Mischungswärmen organischer Substanzen. Thesis (1935)

Excess Enthalpy Data Overview


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