Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 713

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C4H8O2 88.106 141-78-6 Ethyl acetate
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
260.000 0.04980
360.000 0.07300
472.000 0.10230
572.000 0.13760
611.000 0.14780
790.000 0.21670
835.000 0.25710
891.000 0.29170
906.000 0.30700
924.000 0.33000
957.000 0.41450
953.000 0.44100
939.000 0.46420
933.000 0.48580
926.000 0.50580
894.000 0.55690
776.000 0.65050
706.000 0.69850
565.000 0.78570
521.000 0.79970
456.000 0.83090
409.000 0.85020
362.000 0.86990
339.000 0.88190
290.000 0.90020
234.000 0.92160
186.000 0.93980
97.000 0.97000

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Grolier J.-P.E.: Excess Enthalpy. Int.Data Series Sel.Data Mixtures Ser. A 1973 (1973) 17-20


Enthalpy of Mixing Data Set 714

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C4H8O2 88.106 141-78-6 Ethyl acetate
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
370.200 0.06780
500.500 0.10250
742.000 0.16800
853.800 0.22460
995.200 0.32110
1053.900 0.40750
1042.400 0.49410
977.100 0.56980
889.400 0.65300
660.400 0.74010
577.100 0.78050
444.300 0.83710
286.900 0.89900
159.900 0.94380
65.900 0.97960

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Murti P.S.; van Winkle M.: Heats of Mixing and Excess Thermodynamic Properties at 25 °C. of Binary Systems of Methanol, Ethyl Alcohol, 1-Propanol, and 2-Propanol with Ethyl Acetate. Ind.Eng.Chem. Chem.Eng.Data Series 3 (1958) 65-71


Enthalpy of Mixing Data Set 715

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C4H8O2 88.106 141-78-6 Ethyl acetate
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
75.780 0.01230
281.770 0.05240
527.120 0.11500
672.820 0.17060
942.870 0.30420
1014.040 0.38460
1058.000 0.48530
978.870 0.59300
774.560 0.70190
555.170 0.80670
296.840 0.90260
210.180 0.93450
128.950 0.96170

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Nagata I.; Yamada T.; Nakagawa S.: Excess Gibbs Free Energies and Heats of Mixing for Binary Systems Ethyl Acetate with Methanol, Ethanol, 1-Propanol and 2-Propanol. J.Chem.Eng.Data 20 (1975) 271-275

Diagrams

Excess Enthalpies of Ethyl acetate+Methanol
See larger image

List of All References

Source
Nagata I.; Yamada T.; Nakagawa S.: Excess Gibbs Free Energies and Heats of Mixing for Binary Systems Ethyl Acetate with Methanol, Ethanol, 1-Propanol and 2-Propanol. J.Chem.Eng.Data 20 (1975) 271-275
Grolier J.-P.E.: Excess Enthalpy. Int.Data Series Sel.Data Mixtures Ser. A 1973 (1973) 17-20
Murti P.S.; van Winkle M.: Heats of Mixing and Excess Thermodynamic Properties at 25 °C. of Binary Systems of Methanol, Ethyl Alcohol, 1-Propanol, and 2-Propanol with Ethyl Acetate. Ind.Eng.Chem. Chem.Eng.Data Series 3 (1958) 65-71

Excess Enthalpy Data Overview


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