Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 447

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C4H8O2 88.106 141-78-6 Ethyl acetate
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-1109.080 0.21450
-1749.240 0.37660
-1967.380 0.45810
-2035.200 0.58500
-1985.800 0.62550
-1841.350 0.69550
-1778.550 0.71580
-721.385 0.91020

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hirobe H.: Thermochemical Studies. J.Fac.Sci.Univ.Tokyo Sec.1 1 (1926) 155-222


Enthalpy of Mixing Data Set 448

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C4H8O2 88.106 141-78-6 Ethyl acetate
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 308.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-121.100 0.02400
-391.400 0.07700
-778.900 0.15600
-1147.200 0.23800
-1460.000 0.31700
-1698.400 0.39100
-1833.800 0.44600
-1902.100 0.48600
-1957.900 0.55000
-1898.200 0.62400
-1781.700 0.68200
-1569.100 0.74800
-1245.600 0.81800
-1027.300 0.85800
-633.100 0.91700
-176.300 0.97700

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Ohta T.; Asano H.; Nagata I.: Thermodynamic Study of Complex Formation in Four Binary Liquid Mixtures Containing Chloroform. Fluid Phase Equilib. 4 (1980) 105-114


Enthalpy of Mixing Data Set 6156

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C4H8O2 88.106 141-78-6 Ethyl acetate
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 328.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-7.410 0.00200
-9.500 0.00270
-11.770 0.00340
-14.430 0.00410
-16.610 0.00470

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118

Diagrams

Excess Enthalpies of Ethyl acetate+Chloroform
See larger image

List of All References

Source
Ohta T.; Asano H.; Nagata I.: Thermodynamic Study of Complex Formation in Four Binary Liquid Mixtures Containing Chloroform. Fluid Phase Equilib. 4 (1980) 105-114
Hirobe H.: Thermochemical Studies. J.Fac.Sci.Univ.Tokyo Sec.1 1 (1926) 155-222
Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118

Excess Enthalpy Data Overview


© DDBST GmbH