Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 21837

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H8O2 88.106 141-78-6 Ethyl acetate
2 C6H12O2 116.160 123-86-4 Acetic acid butyl ester
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Miscibility gap: No

Constant Value

Temperature 298.000 K
Pressure 1.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
23.200 0.09910
43.700 0.19820
59.400 0.29930
70.000 0.39930
76.000 0.49820
74.700 0.59940
67.000 0.69850
52.400 0.79880
30.000 0.89950

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Laavi H.; Pokki J.-P.; Uusi-Kyyny P.; Massimi A.; Kim Y.; Sapei E.; Alopaeus V.: Vapor–Liquid Equilibrium at 350 K, Excess Molar Enthalpies at 298 K, and Excess Molar Volumes at 298 K of Binary Mixtures Containing Ethyl Acetate, Butyl Acetate, and 2-Butanol. J.Chem.Eng.Data 58 (2013) 1011-1019


Enthalpy of Mixing Data Set 22351

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H8O2 88.106 141-78-6 Ethyl acetate
2 C6H12O2 116.160 123-86-4 Acetic acid butyl ester
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 303.150 K

Data Table

hE [J/mol] x1 [mol/mol]
31.000 0.50000

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Deshpande D.D.; Prabhu C.S.: Heats of Mixing and Contact Interaction of Hydrocarbons with n-Alkyl Acetates. J.Phys.Chem. 85 (1981) 1261-1264

Diagrams

Excess Enthalpies of Ethyl acetate+Acetic acid butyl ester
See larger image

List of All References

Source
Deshpande D.D.; Prabhu C.S.: Heats of Mixing and Contact Interaction of Hydrocarbons with n-Alkyl Acetates. J.Phys.Chem. 85 (1981) 1261-1264
Laavi H.; Pokki J.-P.; Uusi-Kyyny P.; Massimi A.; Kim Y.; Sapei E.; Alopaeus V.: Vapor–Liquid Equilibrium at 350 K, Excess Molar Enthalpies at 298 K, and Excess Molar Volumes at 298 K of Binary Mixtures Containing Ethyl Acetate, Butyl Acetate, and 2-Butanol. J.Chem.Eng.Data 58 (2013) 1011-1019

Excess Enthalpy Data Overview


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