Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 1749

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H8O2 88.106 141-78-6 Ethyl acetate
2 C4H10O 74.123 71-36-3 1-Butanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
326.000 0.05020
347.000 0.05490
371.000 0.06090
391.000 0.06150
459.000 0.07390
473.000 0.08070
585.000 0.09610
656.000 0.11730
814.000 0.14380
824.000 0.14790
930.000 0.16860
952.000 0.17390
1049.000 0.20150
1071.000 0.20230
1092.000 0.20600
1495.000 0.68890
1399.000 0.72120
1427.000 0.72990
1225.000 0.78460
1132.000 0.81940
1079.000 0.82430
904.000 0.86470
872.000 0.86850
631.000 0.91110
409.000 0.94690
353.000 0.95520
329.000 0.95840
317.000 0.95960
228.000 0.97100

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Grolier J.-P.E.: Excess Enthalpy. Int.Data Series Sel.Data Mixtures Ser. A 1973 (1973) 105-114


Enthalpy of Mixing Data Set 1750

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H8O2 88.106 141-78-6 Ethyl acetate
2 C4H10O 74.123 71-36-3 1-Butanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
289.730 0.04370
622.160 0.10010
674.070 0.11110
1108.250 0.21120
1301.680 0.25770
1568.380 0.40570
1665.510 0.48920
1639.130 0.60780
1502.640 0.69380
1167.280 0.81620
737.710 0.90140
450.080 0.94500
256.650 0.96980

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Nagata I.; Nagashima M.; Kazuma K.; Nagagawa M.: Heats of Mixing for Binary Systems and Data Reduction Based on a Triplet Model of Guggenheim. J.Chem.Eng.Japan 8 (1975) 261-265


Enthalpy of Mixing Data Set 1751

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H8O2 88.106 141-78-6 Ethyl acetate
2 C4H10O 74.123 71-36-3 1-Butanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 308.150 K

Data Table

hE [J/mol] x1 [mol/mol]
356.300 0.05380
400.680 0.05900
678.680 0.10930
1120.390 0.20940
1395.460 0.31160
1418.910 0.31390
1606.890 0.41480
1719.100 0.52180
1721.190 0.52370
1702.350 0.57800
1629.500 0.64920
1414.720 0.74780
1188.210 0.81360
1183.610 0.81630
701.710 0.90720
386.020 0.95320
377.230 0.95420
379.740 0.95490

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Nagata I.; Nagashima M.; Kazuma K.; Nagagawa M.: Heats of Mixing for Binary Systems and Data Reduction Based on a Triplet Model of Guggenheim. J.Chem.Eng.Japan 8 (1975) 261-265

Diagrams

Excess Enthalpies of Ethyl acetate+1-Butanol
See larger image

List of All References

Source
Grolier J.-P.E.: Excess Enthalpy. Int.Data Series Sel.Data Mixtures Ser. A 1973 (1973) 105-114
Nagata I.; Nagashima M.; Kazuma K.; Nagagawa M.: Heats of Mixing for Binary Systems and Data Reduction Based on a Triplet Model of Guggenheim. J.Chem.Eng.Japan 8 (1975) 261-265

Excess Enthalpy Data Overview


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