Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 16512

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 C2H6O 46.069 64-17-5 Ethanol
3 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 308.150 K
Pressure 75.000 bar

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
-133.000 0.04420 0.71690
-339.000 0.08890 0.68330
-531.000 0.13420 0.64940
-782.000 0.18000 0.61500
-998.000 0.22650 0.58010
-1226.000 0.27350 0.54490
-1482.000 0.32110 0.50920
-1681.000 0.36930 0.47300
-1939.000 0.41810 0.43640
-2189.000 0.46760 0.39930
-2434.000 0.51770 0.36170
-2662.000 0.56850 0.32360
-2901.000 0.61990 0.28510
-3137.000 0.67200 0.24600
-3316.000 0.72490 0.20630
-3481.000 0.77840 0.16620
-3625.000 0.83270 0.12550
-3718.000 0.88770 0.08420
-3625.000 0.92480 0.05640
-1409.000 0.96220 0.02840

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Ochi K.; Dai W.; Wada Y.; Hayashi H.; Kurihara K.; Kojima K.: Measurement and Correlation of Excess Molar Enthalpies for the Systems Containing Supercritical Carbon Dioxide and Alcohols. Fluid Phase Equilib. 194-197 (2002) 919-928


Enthalpy of Mixing Data Set 16513

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 C2H6O 46.069 64-17-5 Ethanol
3 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 308.150 K
Pressure 75.000 bar

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
-60.000 0.03490 0.48260
-157.000 0.07090 0.46460
-258.000 0.10810 0.44600
-400.000 0.14660 0.42670
-554.000 0.18630 0.40690
-725.000 0.22750 0.38630
-915.000 0.27000 0.36500
-1137.000 0.31410 0.34300
-1306.000 0.35980 0.32010
-1546.000 0.40720 0.29640
-1792.000 0.45640 0.27180
-1987.000 0.50750 0.24630
-2226.000 0.56060 0.21970
-2424.000 0.61580 0.19210
-2643.000 0.67330 0.16340
-2890.000 0.73320 0.13340
-3094.000 0.79560 0.10220
-3199.000 0.86080 0.06960
-3057.000 0.90580 0.04710
-2026.000 0.95220 0.02390

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Ochi K.; Dai W.; Wada Y.; Hayashi H.; Kurihara K.; Kojima K.: Measurement and Correlation of Excess Molar Enthalpies for the Systems Containing Supercritical Carbon Dioxide and Alcohols. Fluid Phase Equilib. 194-197 (2002) 919-928


Enthalpy of Mixing Data Set 16514

Components

No. Formula Molar Mass CAS Registry Number Name
1 CO2 44.010 124-38-9 Carbon dioxide
2 C2H6O 46.069 64-17-5 Ethanol
3 H2O 18.015 7732-18-5 Water
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 308.150 K
Pressure 75.000 bar

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
-124.000 0.08150 0.22960
-244.000 0.11170 0.22210
-411.000 0.14360 0.21410
-567.000 0.17730 0.20570
-754.000 0.21310 0.19670
-896.000 0.25110 0.18720
-1016.000 0.29150 0.17710
-1214.000 0.33460 0.16640
-1373.000 0.38070 0.15480
-1537.000 0.43000 0.14250
-1730.000 0.48290 0.12930
-1977.000 0.53990 0.11500
-2202.000 0.60140 0.09970
-2427.000 0.66800 0.08300
-2469.000 0.74030 0.06490
-2332.000 0.81910 0.04520
-1403.000 0.87560 0.03110
-334.000 0.93580 0.01610

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Ochi K.; Dai W.; Wada Y.; Hayashi H.; Kurihara K.; Kojima K.: Measurement and Correlation of Excess Molar Enthalpies for the Systems Containing Supercritical Carbon Dioxide and Alcohols. Fluid Phase Equilib. 194-197 (2002) 919-928

List of All References

Source
Ochi K.; Dai W.; Wada Y.; Hayashi H.; Kurihara K.; Kojima K.: Measurement and Correlation of Excess Molar Enthalpies for the Systems Containing Supercritical Carbon Dioxide and Alcohols. Fluid Phase Equilib. 194-197 (2002) 919-928

Excess Enthalpy Data Overview


© DDBST GmbH