Dortmund Data Bank
Excess Enthalpy Data
The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.
Enthalpy of Mixing Data Set 683
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 2 |
C2H6O |
46.069 |
64-17-5 |
Ethanol |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| 2.800 |
0.24120 |
| 4.500 |
0.47580 |
| 4.300 |
0.72860 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Chand A.; Fenby D.V.: Enthalpy of deuterium exchange reactions in water + ethanol and methanol + ethanol. J.Chem.Thermodyn. 10 (1978) 997-1001 |
Enthalpy of Mixing Data Set 684
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 2 |
C2H6O |
46.069 |
64-17-5 |
Ethanol |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| 2.512 |
0.44210 |
| 7.536 |
0.61100 |
| 8.792 |
0.70820 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Hirobe H.: Thermochemical Studies. J.Fac.Sci.Univ.Tokyo Sec.1 1 (1926) 155-222 |
Enthalpy of Mixing Data Set 685
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 2 |
C2H6O |
46.069 |
64-17-5 |
Ethanol |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| 0.900 |
0.07340 |
| 1.700 |
0.14600 |
| 2.500 |
0.23480 |
| 3.200 |
0.31670 |
| 3.900 |
0.39740 |
| 4.400 |
0.47120 |
| 4.600 |
0.53940 |
| 4.700 |
0.60020 |
| 4.600 |
0.65190 |
| 4.400 |
0.69650 |
| 3.500 |
0.79980 |
| 2.700 |
0.85350 |
| 1.900 |
0.90490 |
| 1.200 |
0.94650 |
| 0.600 |
0.97560 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Pflug H.D.; Pope A.E.; Benson G.C.: Heats of Mixing of Normal Alcohols at 25 °C. J.Chem.Eng.Data 13 (1968) 408-410 |
Diagrams
List of All References
| Source |
| Hirobe H.: Thermochemical Studies. J.Fac.Sci.Univ.Tokyo Sec.1 1 (1926) 155-222 |
| Pflug H.D.; Pope A.E.; Benson G.C.: Heats of Mixing of Normal Alcohols at 25 °C. J.Chem.Eng.Data 13 (1968) 408-410 |
| Chand A.; Fenby D.V.: Enthalpy of deuterium exchange reactions in water + ethanol and methanol + ethanol. J.Chem.Thermodyn. 10 (1978) 997-1001 |
Excess Enthalpy Data Overview
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