Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 1108

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 60-29-7 Diethyl ether
2 C2H6O 46.069 64-17-5 Ethanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 290.150 K

Data Table

hE [J/mol] x1 [mol/mol]
59.453 0.05000
96.296 0.08000
177.939 0.15000
394.815 0.40000
439.614 0.46000
502.416 0.58000
510.790 0.62400
514.976 0.65000
514.976 0.71000
445.894 0.79300
443.801 0.81000
309.823 0.89900

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Calvet E.: Sur le Mechanisme de la Dissolution. Etude au Microcalorimetre. Mem.Services Chim.Etat.(Paris) 32 (1945) 168-219


Enthalpy of Mixing Data Set 1109

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 60-29-7 Diethyl ether
2 C2H6O 46.069 64-17-5 Ethanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 273.150 K

Data Table

hE [J/mol] x1 [mol/mol]
464.735 0.36900
510.790 0.41900
544.284 0.45300
556.844 0.47700
581.965 0.50400
573.592 0.53500
594.525 0.55000
594.525 0.58700
602.899 0.60000
607.086 0.62100
623.833 0.63900
602.899 0.64100
611.273 0.67800
611.273 0.71300
598.712 0.74600
581.965 0.77600
548.471 0.81300
489.855 0.85200
397.746 0.88500

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Desmaroux M.: Étude expérimentale du mélange anhydre d'alcool et d'éther éthylique. Mem.Poudres 23 (1928) 198-229


Enthalpy of Mixing Data Set 1110

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 60-29-7 Diethyl ether
2 C2H6O 46.069 64-17-5 Ethanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
40.193 0.03050
254.557 0.16200
433.752 0.28090
477.714 0.33250
568.986 0.41110
677.424 0.56210
667.794 0.72440
382.255 0.91180

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Hirobe H.: Thermochemical Studies. J.Fac.Sci.Univ.Tokyo Sec.1 1 (1926) 155-222

Diagrams

Excess Enthalpies of Ethanol+Diethyl ether
See larger image

List of All References

Source
Hirobe H.: Thermochemical Studies. J.Fac.Sci.Univ.Tokyo Sec.1 1 (1926) 155-222
Desmaroux M.: Étude expérimentale du mélange anhydre d'alcool et d'éther éthylique. Mem.Poudres 23 (1928) 198-229
Calvet E.: Sur le Mechanisme de la Dissolution. Etude au Microcalorimetre. Mem.Services Chim.Etat.(Paris) 32 (1945) 168-219

Excess Enthalpy Data Overview


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