Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 4439

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 60-29-7 Diethyl ether
2 H2O 18.015 7732-18-5 Water
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Miscibility gap: Yes

Constant Value

Temperature 308.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-43.900 0.00290
-70.100 0.00460
-93.800 0.00630
-115.300 0.00780
-158.800 0.01170
276.300 0.95260
278.800 0.95550
226.600 0.96640
210.800 0.96880
190.800 0.97310
143.500 0.98000
115.500 0.98500
91.800 0.98760

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Villamanan M.A.; Allawi A.J.; van Ness H.C.: Vapor-Liquid-Liquid Equilibrium and Heats of Mixing for Diethyl Ether/Water at 35 °C. J.Chem.Eng.Data 29 (1984) 431-435


Enthalpy of Mixing Data Set 14453

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 60-29-7 Diethyl ether
2 H2O 18.015 7732-18-5 Water
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Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-263.768 0.01590
-242.834 0.05000
-217.714 0.10000
-188.406 0.15000
-159.098 0.20000
-129.791 0.25000
-104.670 0.30000
-75.362 0.35000
-46.055 0.40000
-16.747 0.45000
8.374 0.50000
37.681 0.55000
66.989 0.60000
96.296 0.65000
121.417 0.70000
150.725 0.75000
180.032 0.80000
209.340 0.85000
234.461 0.90000
263.768 0.95000
263.768 0.95020

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Signer R.; Arm H.; Daeniker H.: 8. Mitteilung: Dampfdrücke, Dichten, thermodynamische Mischungsfunktionen und Brechungsindices der binären Systeme Wasser - Tetrahydrofuran und Wasser - Diäthyläther bei 25 °C. Helv.Chim.Acta 52 (1969) 2347-2351

Diagrams

Excess Enthalpies of Diethyl ether+Water
See larger image

List of All References

Source
Signer R.; Arm H.; Daeniker H.: 8. Mitteilung: Dampfdrücke, Dichten, thermodynamische Mischungsfunktionen und Brechungsindices der binären Systeme Wasser - Tetrahydrofuran und Wasser - Diäthyläther bei 25 °C. Helv.Chim.Acta 52 (1969) 2347-2351
Villamanan M.A.; Allawi A.J.; van Ness H.C.: Vapor-Liquid-Liquid Equilibrium and Heats of Mixing for Diethyl Ether/Water at 35 °C. J.Chem.Eng.Data 29 (1984) 431-435

Excess Enthalpy Data Overview


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