Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 6222

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 60-29-7 Diethyl ether
2 C6H14 86.177 110-54-3 Hexane
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Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
15.190 0.98990
12.620 0.99160
11.470 0.99240
10.040 0.99330
8.890 0.99410
7.510 0.99500
4.980 0.99660

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118


Enthalpy of Mixing Data Set 11469

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 60-29-7 Diethyl ether
2 C6H14 86.177 110-54-3 Hexane
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
131.000 0.91500
96.700 0.94200
57.400 0.95700
63.500 0.96100
31.900 0.97700

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Koldobskaya L.L.; Gaile A.A.; Semenov L.V.; Zhmaev E.G.; Kuznetsova S.Yu.; Rumyantseva N.V.: Mischungsenthalpie von Kohlenwasserstoffen mit sauerstoff- und stickstoffhaltigen polaren Lösungsmitteln. Viniti (1987) 1-17

Diagrams

Excess Enthalpies of Diethyl ether+Hexane
See larger image

List of All References

Source
Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118
Koldobskaya L.L.; Gaile A.A.; Semenov L.V.; Zhmaev E.G.; Kuznetsova S.Yu.; Rumyantseva N.V.: Mischungsenthalpie von Kohlenwasserstoffen mit sauerstoff- und stickstoffhaltigen polaren Lösungsmitteln. Viniti (1987) 1-17

Excess Enthalpy Data Overview


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