Dortmund Data Bank
Excess Enthalpy Data
The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.
Enthalpy of Mixing Data Set 456
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
C4H10O |
74.123 |
60-29-7 |
Diethyl ether |
| 2 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -1029.000 |
0.12740 |
| -2129.000 |
0.30060 |
| -2547.000 |
0.40160 |
| -2634.000 |
0.46220 |
| -2609.000 |
0.52910 |
| -2513.000 |
0.59100 |
| -2108.000 |
0.69460 |
| -1201.000 |
0.85130 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Beath L.A.; Williamson A.G.: I. Enthalpies of Mixing of Ethers with Carbon Tetrachloride and with Chloroform. J.Chem.Thermodyn. 1 (1969) 51-57 |
Enthalpy of Mixing Data Set 457
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
C4H10O |
74.123 |
60-29-7 |
Diethyl ether |
| 2 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -219.807 |
0.02500 |
| -439.614 |
0.05000 |
| -653.141 |
0.07500 |
| -857.038 |
0.10000 |
| -1057.580 |
0.12500 |
| -1248.500 |
0.15000 |
| -1433.140 |
0.17500 |
| -1608.990 |
0.20000 |
| -1773.530 |
0.22500 |
| -1923.830 |
0.25000 |
| -2068.700 |
0.27500 |
| -2200.160 |
0.30000 |
| -2319.490 |
0.32500 |
| -2423.740 |
0.35000 |
| -2515.010 |
0.37500 |
| -2589.120 |
0.40000 |
| -2645.220 |
0.42500 |
| -2696.300 |
0.45000 |
| -2727.280 |
0.47500 |
| -2732.300 |
0.50000 |
| -2717.650 |
0.52500 |
| -2687.090 |
0.55000 |
| -2637.260 |
0.57500 |
| -2572.370 |
0.60000 |
| -2493.660 |
0.62500 |
| -2399.450 |
0.65000 |
| -2294.370 |
0.67500 |
| -2174.200 |
0.70000 |
| -2041.480 |
0.72500 |
| -1897.460 |
0.75000 |
| -1744.220 |
0.77500 |
| -1581.350 |
0.80000 |
| -1411.370 |
0.82500 |
| -1230.080 |
0.85000 |
| -1041.680 |
0.87500 |
| -846.571 |
0.90000 |
| -645.186 |
0.92500 |
| -435.427 |
0.95000 |
| -220.226 |
0.97500 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Becker F.; Kiefer M.: III. Äther-Chloroform-Systeme. Z.Naturforsch.A 26 (1971) 1040-1046 |
Enthalpy of Mixing Data Set 458
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
C4H10O |
74.123 |
60-29-7 |
Diethyl ether |
| 2 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -791.305 |
0.09000 |
| -1096.940 |
0.13300 |
| -1360.710 |
0.16700 |
| -1444.450 |
0.17800 |
| -2223.190 |
0.29800 |
| -2524.640 |
0.39300 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Chevalier J.-L.; Bares D.: I. Chaleurs de mélange à 25 °C. J.Chim.Phys.Phys.-Chim.Biol. 66 (1969) 1448-1452 |
Diagrams
List of All References
| Source |
| Beath L.A.; Williamson A.G.: I. Enthalpies of Mixing of Ethers with Carbon Tetrachloride and with Chloroform. J.Chem.Thermodyn. 1 (1969) 51-57 |
| Chevalier J.-L.; Bares D.: I. Chaleurs de mélange à 25 °C. J.Chim.Phys.Phys.-Chim.Biol. 66 (1969) 1448-1452 |
| Becker F.; Kiefer M.: III. Äther-Chloroform-Systeme. Z.Naturforsch.A 26 (1971) 1040-1046 |
Excess Enthalpy Data Overview
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