Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 9450

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 H2O 18.015 7732-18-5 Water
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Miscibility gap: No

Constant Value

Temperature 353.200 K
Pressure 0.3393 bar

Data Table

hE [J/mol] x1 [mol/mol]
18.800 0.41800
18.500 0.47500
19.200 0.47700
20.100 0.51000
18.900 0.55400
18.900 0.57800

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Lancaster N.; Wormald C.J.: The Enthalpy of Mixing of (Water + Trichloromethane) Vapour. Z.Phys.Chem.(München) 128 (1981) 43-49


Enthalpy of Mixing Data Set 9451

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 H2O 18.015 7732-18-5 Water
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Miscibility gap: No

Constant Value

Temperature 373.200 K
Pressure 0.6711 bar

Data Table

hE [J/mol] x1 [mol/mol]
31.700 0.41700
33.400 0.50700
32.500 0.52500
31.300 0.59600
33.200 0.62600
29.200 0.67500

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Lancaster N.; Wormald C.J.: The Enthalpy of Mixing of (Water + Trichloromethane) Vapour. Z.Phys.Chem.(München) 128 (1981) 43-49


Enthalpy of Mixing Data Set 9452

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 H2O 18.015 7732-18-5 Water
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Miscibility gap: No

Constant Value

Temperature 383.200 K
Pressure 0.752 bar

Data Table

hE [J/mol] x1 [mol/mol]
34.200 0.46200
35.400 0.47500
35.600 0.48000
34.600 0.50300
34.200 0.52600
34.200 0.57000

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Lancaster N.; Wormald C.J.: The Enthalpy of Mixing of (Water + Trichloromethane) Vapour. Z.Phys.Chem.(München) 128 (1981) 43-49

Diagrams

Excess Enthalpies of Chloroform+Water
See larger image

List of All References

Source
Lancaster N.; Wormald C.J.: The Enthalpy of Mixing of (Water + Trichloromethane) Vapour. Z.Phys.Chem.(München) 128 (1981) 43-49

Excess Enthalpy Data Overview


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