Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 442

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C4H8O 72.107 109-99-9 Tetrahydrofuran
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-217.295 0.02500
-429.147 0.05000
-636.394 0.07500
-838.197 0.10000
-1034.140 0.12500
-1223.800 0.15000
-1406.770 0.17500
-1582.610 0.20000
-1750.500 0.22500
-1910.020 0.25000
-2060.320 0.27500
-2199.740 0.30000
-2329.120 0.32500
-2445.930 0.35000
-2549.760 0.37500
-2640.200 0.40000
-2715.980 0.42500
-2775.850 0.45000
-2818.130 0.47500
-2844.510 0.50000
-2851.210 0.52500
-2836.980 0.55000
-2803.480 0.57500
-2751.980 0.60000
-2683.320 0.62500
-2596.650 0.65000
-2494.080 0.67500
-2375.170 0.70000
-2241.610 0.72500
-2093.400 0.75000
-1931.370 0.77500
-1757.200 0.80000
-1570.890 0.82500
-1374.110 0.85000
-1166.860 0.87500
-949.985 0.90000
-724.735 0.92500
-490.693 0.95000
-248.696 0.97500

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Becker F.; Fries E.W.; Kiefer M.; Pflug H.D.: II. Zweistufen-Gleichgewichtsmodelle. Z.Naturforsch.A 25 (1970) 677-688


Enthalpy of Mixing Data Set 443

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C4H8O 72.107 109-99-9 Tetrahydrofuran
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 303.150 K
Pressure 2.100 bar

Data Table

hE [J/mol] x1 [mol/mol]
-115.900 0.01380
-213.300 0.02550
-326.400 0.03930
-573.400 0.06960
-800.800 0.09870
-990.900 0.12380
-1294.700 0.16560
-1618.400 0.21380
-1887.500 0.25780
-2099.700 0.29650
-2256.500 0.32880
-2419.000 0.36800
-2548.600 0.40720
-2639.700 0.44530
-2697.600 0.48670
-2708.800 0.53070
-2678.500 0.57040
-2617.500 0.60390
-2513.100 0.64130
-2355.900 0.68240
-2145.000 0.72610
-1989.500 0.75350
-1779.100 0.78710
-1624.800 0.80960
-1428.600 0.83660
-1261.400 0.85830
-1031.100 0.88660
-857.400 0.90720
-619.700 0.93410
-419.200 0.95600
-234.000 0.97560
-141.200 0.98530
-69.500 0.99270

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
van Ness H.C.; Abbott M.M.: Excess Enthalpy. Int.Data Series Sel.Data Mixtures Ser. A 1974 (1974) 63-68


Enthalpy of Mixing Data Set 444

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C4H8O 72.107 109-99-9 Tetrahydrofuran
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 318.150 K
Pressure 2.100 bar

Data Table

hE [J/mol] x1 [mol/mol]
-117.300 0.01440
-316.800 0.03920
-546.800 0.06840
-777.500 0.09880
-997.500 0.12860
-1256.200 0.16580
-1531.600 0.20810
-1733.400 0.24170
-1952.000 0.28190
-2097.300 0.31180
-2200.600 0.33550
-2313.100 0.36440
-2406.800 0.39340
-2479.900 0.42070
-2541.800 0.45230
-2571.900 0.56330
-2526.100 0.59340
-2440.900 0.62930
-2317.900 0.66690
-2159.700 0.70480
-1965.000 0.74350
-1726.900 0.78420
-1479.100 0.82170
-1268.700 0.85100
-1120.600 0.87040
-898.500 0.89830
-679.200 0.92460
-474.100 0.94810
-276.700 0.97020
-109.600 0.98830

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
van Ness H.C.; Abbott M.M.: Excess Enthalpy. Int.Data Series Sel.Data Mixtures Ser. A 1974 (1974) 63-68

Diagrams

Excess Enthalpies of Chloroform+Tetrahydrofuran
See larger image

List of All References

Source
Becker F.; Fries E.W.; Kiefer M.; Pflug H.D.: II. Zweistufen-Gleichgewichtsmodelle. Z.Naturforsch.A 25 (1970) 677-688
van Ness H.C.; Abbott M.M.: Excess Enthalpy. Int.Data Series Sel.Data Mixtures Ser. A 1974 (1974) 63-68

Excess Enthalpy Data Overview


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