Dortmund Data Bank
Excess Enthalpy Data
The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.
Enthalpy of Mixing Data Set 502
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
| 2 |
C6H14 |
86.177 |
110-54-3 |
Hexane |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| 276.000 |
0.10600 |
| 468.000 |
0.19200 |
| 605.000 |
0.28100 |
| 718.000 |
0.41000 |
| 750.000 |
0.49600 |
| 761.000 |
0.49900 |
| 738.000 |
0.60300 |
| 670.000 |
0.69800 |
| 527.000 |
0.79500 |
| 287.000 |
0.90700 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Bissell T.G.; Okafor G.E.; Williamson A.G.: Enthalpies and Volumes of Mixing of Alkanes with Carbon Tetrachloride, Chloroform, and Methylene Chloride at 25 °C. J.Chem.Thermodyn. 3 (1971) 393-399 |
Enthalpy of Mixing Data Set 503
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
| 2 |
C6H14 |
86.177 |
110-54-3 |
Hexane |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| 67.030 |
0.05980 |
| 132.900 |
0.11020 |
| 228.250 |
0.18030 |
| 450.380 |
0.34990 |
| 518.170 |
0.42010 |
| 586.040 |
0.58000 |
| 572.110 |
0.62970 |
| 471.960 |
0.75020 |
| 405.060 |
0.80010 |
| 344.820 |
0.83980 |
| 249.780 |
0.89030 |
| 162.150 |
0.92990 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Sharma B.R.; Pundeer G.S.; Singh P.P.: Thermodynamics of weak Interactions: Excess Enthalpies and Excess Gibbs Free Energies of Mixing. Thermochim.Acta 11 (1975) 105-114 |
Enthalpy of Mixing Data Set 6157
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
| 2 |
C6H14 |
86.177 |
110-54-3 |
Hexane |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| 8.510 |
0.00360 |
| 10.540 |
0.00450 |
| 12.700 |
0.00540 |
| 17.140 |
0.00720 |
| 22.440 |
0.00900 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118 |
Diagrams
List of All References
| Source |
| Bissell T.G.; Okafor G.E.; Williamson A.G.: Enthalpies and Volumes of Mixing of Alkanes with Carbon Tetrachloride, Chloroform, and Methylene Chloride at 25 °C. J.Chem.Thermodyn. 3 (1971) 393-399 |
| Sharma B.R.; Pundeer G.S.; Singh P.P.: Thermodynamics of weak Interactions: Excess Enthalpies and Excess Gibbs Free Energies of Mixing. Thermochim.Acta 11 (1975) 105-114 |
| Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118 |
Excess Enthalpy Data Overview
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