Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 756

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C6H6 78.114 71-43-2 Benzene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 308.150 K

Data Table

hE [J/mol] x1 [mol/mol]
800.000 0.38100
545.000 0.65800
545.000 0.65900

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Brown I.; Fock W.: IV. Systems of n-Alcohols with Benzene at 25, 35, and 45° C. Aust.J.Chem. 14 (1961) 387-396


Enthalpy of Mixing Data Set 757

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C6H6 78.114 71-43-2 Benzene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
435.427 0.05010
539.260 0.07920
589.920 0.10670
632.207 0.13260
656.909 0.15700
692.915 0.20190
711.337 0.26090
707.150 0.32730
690.403 0.37950
658.583 0.43770
625.927 0.48600
575.266 0.54800
525.025 0.60150
400.677 0.70740
347.504 0.75110
279.678 0.80510
224.831 0.84470
162.866 0.89050
72.850 0.95230

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Coca Prados J.: Propiedades Fisico - Quimicas de Mezclas Liquidas Binarias: Viscosidad y Calor de Mezcla. Thesis (1969)


Enthalpy of Mixing Data Set 758

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C6H6 78.114 71-43-2 Benzene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
483.156 0.06180
622.577 0.11780
694.171 0.19020
731.853 0.25580
719.292 0.35010
681.192 0.42810
647.698 0.49370
560.194 0.55750
588.245 0.57320
513.302 0.61500
512.045 0.63830
466.828 0.65620
413.656 0.69930
369.694 0.73170
327.408 0.76410
281.771 0.79750
238.229 0.83080
194.267 0.86430
144.863 0.89830
91.272 0.93220
43.124 0.96010
14.235 0.98620

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Deshpande D.D.; Pandya M.V.: Part 1. Heats of Mixing of Aniline in Benzene, Carbontetrachloride and Chlorobenzene. Trans.Faraday Soc. 61 (1965) 1858-1868

Diagrams

Excess Enthalpies of Benzene+Methanol
See larger image

List of All References

Source
Deshpande D.D.; Pandya M.V.: Part 1. Heats of Mixing of Aniline in Benzene, Carbontetrachloride and Chlorobenzene. Trans.Faraday Soc. 61 (1965) 1858-1868
Brown I.; Fock W.: IV. Systems of n-Alcohols with Benzene at 25, 35, and 45° C. Aust.J.Chem. 14 (1961) 387-396
Coca Prados J.: Propiedades Fisico - Quimicas de Mezclas Liquidas Binarias: Viscosidad y Calor de Mezcla. Thesis (1969)

Excess Enthalpy Data Overview


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