Dortmund Data Bank
Excess Enthalpy Data
The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.
Enthalpy of Mixing Data Set 392
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
| 2 |
C2H3N |
41.053 |
75-05-8 |
Acetonitrile |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -119.500 |
0.07310 |
| -162.600 |
0.09960 |
| -369.100 |
0.20510 |
| -500.600 |
0.27610 |
| -689.800 |
0.38840 |
| -808.500 |
0.50070 |
| -855.000 |
0.59430 |
| -809.000 |
0.69230 |
| -735.600 |
0.74440 |
| -606.400 |
0.81980 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Handa Y.P.; Jones D.E.: Molar Excess Enthalpies of Acetonitrile + Chloroform and of Acetonitrile + Chloroform-D1 at 298 K. Can.J.Chem. 55 (1977) 2977-2979 |
Enthalpy of Mixing Data Set 393
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
| 2 |
C2H3N |
41.053 |
75-05-8 |
Acetonitrile |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -24.800 |
0.01400 |
| -79.300 |
0.04800 |
| -197.600 |
0.11600 |
| -325.100 |
0.18600 |
| -438.700 |
0.24900 |
| -534.700 |
0.30500 |
| -612.800 |
0.35300 |
| -683.100 |
0.40100 |
| -759.100 |
0.47700 |
| -810.300 |
0.55200 |
| -821.100 |
0.62500 |
| -751.400 |
0.72300 |
| -607.300 |
0.81000 |
| -365.600 |
0.90000 |
| -115.700 |
0.97200 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Nagata I.; Kawamura Y.: Excess Thermodynamic Functions and Complex Formation in Binary Liquid Mixtures Containing Acetonitrile. Fluid Phase Equilib. 3 (1979) 1-11 |
Enthalpy of Mixing Data Set 6279
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CHCl3 |
119.377 |
67-66-3 |
Chloroform |
| 2 |
C2H3N |
41.053 |
75-05-8 |
Acetonitrile |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| -4.020 |
0.00270 |
| -5.790 |
0.00410 |
| -7.740 |
0.00540 |
| -9.870 |
0.00680 |
| -11.890 |
0.00810 |
| -14.140 |
0.00950 |
| -16.310 |
0.01090 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118 |
Diagrams
List of All References
| Source |
| Nagata I.; Kawamura Y.: Excess Thermodynamic Functions and Complex Formation in Binary Liquid Mixtures Containing Acetonitrile. Fluid Phase Equilib. 3 (1979) 1-11 |
| Handa Y.P.; Jones D.E.: Molar Excess Enthalpies of Acetonitrile + Chloroform and of Acetonitrile + Chloroform-D1 at 298 K. Can.J.Chem. 55 (1977) 2977-2979 |
| Trampe D.M.; Eckert C.A.: Calorimetric Measurement of Partial Molar Excess Enthalpies at Infinite Dilution. J.Chem.Eng.Data 36 (1991) 112-118 |
Excess Enthalpy Data Overview
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