Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 3922

Components

No. Formula Molar Mass CAS Registry Number Name
1 C3H6O 58.080 67-64-1 Acetone
2 CHCl3 119.377 67-66-3 Chloroform
3 CH4O 32.042 67-56-1 Methanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 323.150 K

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
-160.400 0.04890 0.00520
-53.300 0.04690 0.04420
59.000 0.04480 0.08810
144.300 0.04310 0.12400
229.100 0.04110 0.16300
299.600 0.03930 0.20000
372.800 0.03710 0.24500
433.800 0.03480 0.29140
-348.500 0.22840 0.07120
-270.400 0.21190 0.13850
-131.900 0.18690 0.24000
-30.100 0.16870 0.31400
53.600 0.15290 0.37820
84.400 0.14640 0.40450
-14.400 0.49220 0.01140
-244.400 0.46080 0.07460
-430.700 0.41810 0.16020
-519.400 0.36580 0.26540
-513.600 0.32150 0.35430
-472.900 0.28420 0.42930
-451.200 0.26960 0.45840
471.400 0.74500 0.00870
123.900 0.70980 0.05550
-224.200 0.66810 0.11100
-516.300 0.62450 0.16900
-751.000 0.57840 0.23040
-936.700 0.52370 0.30320
-1023.500 0.47840 0.36340
-1058.800 0.42320 0.43690
-1049.700 0.39280 0.47740
307.400 0.95300 0.00350
-106.200 0.90770 0.05090
-437.400 0.86490 0.09560
-771.600 0.81650 0.14630
-1020.800 0.77360 0.19110
-1262.500 0.72280 0.24420
-1458.400 0.66800 0.30150
-1589.800 0.60690 0.36540
-1657.600 0.52930 0.44660
-1645.100 0.49010 0.48750
-1608.400 0.45260 0.52680
107.800 0.00610 0.04980
-93.400 0.06050 0.04700
-245.000 0.11640 0.04420
-361.200 0.19170 0.04050
-383.100 0.26800 0.03660
-371.000 0.29510 0.03530
506.500 0.00650 0.24490
224.800 0.06860 0.22960
14.200 0.12320 0.21620
-182.200 0.18680 0.20050
-334.300 0.25810 0.18290
-423.000 0.34190 0.16220
-429.700 0.35940 0.15790
738.400 0.00480 0.48710
445.500 0.06200 0.45910
169.600 0.12040 0.43050
-76.500 0.17870 0.40200
-306.900 0.24300 0.37050
-483.200 0.30490 0.34020
570.600 0.00760 0.75280
256.900 0.06780 0.70720
-108.100 0.14240 0.65060
-391.700 0.20620 0.60220
-616.800 0.26370 0.55860
-830.900 0.32730 0.51030
-1009.100 0.39490 0.45900
-1114.900 0.45220 0.41560
-1145.300 0.47600 0.39750
155.100 0.00680 0.93710
-154.600 0.06930 0.87810
-468.300 0.13510 0.81610
-763.500 0.20140 0.75350
-1055.600 0.27410 0.68490
-1256.100 0.33530 0.62720
-1427.100 0.39190 0.57380
-1552.200 0.45100 0.51800
-1621.200 0.50410 0.46790
-1632.400 0.51680 0.45590
-269.000 0.95670 0.04030
-73.100 0.93230 0.03930
164.400 0.88710 0.03730
311.600 0.75010 0.03160
92.000 0.57340 0.02410
-96.900 0.46920 0.01980
-239.500 0.38580 0.01620
-280.800 0.35800 0.01510
-1393.400 0.74790 0.24770
-1083.900 0.70920 0.23490
-808.900 0.65830 0.21800
-518.900 0.55490 0.18370
-426.700 0.48050 0.15920
-381.700 0.40070 0.13270
-365.500 0.33680 0.11160
-355.200 0.28450 0.09420
-349.000 0.25890 0.08570
-1586.500 0.42070 0.57070
-1348.300 0.40260 0.54620
-1018.100 0.37210 0.50490
-733.700 0.33820 0.45900
-444.200 0.28960 0.39280
-258.900 0.24390 0.33100
-128.600 0.19480 0.26430
-69.900 0.16030 0.21740
-57.400 0.15110 0.20510
-1144.400 0.26630 0.72560
-851.300 0.24990 0.68090
-567.800 0.23030 0.62750
-332.800 0.20960 0.57100
-115.900 0.18380 0.50060
62.700 0.15070 0.41080
149.900 0.12100 0.32990
176.700 0.09990 0.27230
180.300 0.08810 0.24000
-126.800 0.04500 0.92920
98.000 0.04200 0.86770
286.300 0.03880 0.80310
456.200 0.03520 0.72700
573.100 0.03150 0.65080
647.800 0.02720 0.56180
667.100 0.02230 0.46080
641.900 0.01890 0.39050
610.900 0.01680 0.34630

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Morris J.W.; Mulvey P.J.; Abbott M.M.; van Ness H.C.: I. Acetone-Chloroform-Methanol at 50 °C. J.Chem.Eng.Data 20 (1975) 403-405


Enthalpy of Mixing Data Set 4234

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 CHCl3 119.377 67-66-3 Chloroform
3 C3H6O 58.080 67-64-1 Acetone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
-947.200 0.05130 0.23610
-821.400 0.08320 0.22820
-649.300 0.13150 0.21620
-470.900 0.19060 0.20150
-306.800 0.25790 0.18470
-218.500 0.30050 0.17410
-100.300 0.36990 0.15680
-18.100 0.43060 0.14170
57.100 0.50640 0.12280
102.800 0.57380 0.10610
119.300 0.61350 0.09620
132.700 0.66980 0.08220
134.000 0.72720 0.06790
131.300 0.75660 0.06060
124.400 0.78790 0.05280
118.900 0.80680 0.04810
115.800 0.81590 0.04580
-1682.300 0.03840 0.48060
-1407.800 0.10090 0.44950
-1160.100 0.17420 0.41280
-988.400 0.23800 0.38100
-816.500 0.31650 0.34170
-669.200 0.40020 0.29990
-552.600 0.48050 0.25970
-457.200 0.55710 0.22140
-405.300 0.60170 0.19910
-379.600 0.62830 0.18580
-329.600 0.67830 0.16080
-294.100 0.71430 0.14280
-269.000 0.74010 0.13000
-245.000 0.76490 0.11750
-222.200 0.78850 0.10570
-1522.600 0.00980 0.74290
-1325.000 0.04960 0.71310
-1098.700 0.11780 0.66190
-952.000 0.19110 0.60690
-876.000 0.24820 0.56410
-825.400 0.29820 0.52600
-787.300 0.34820 0.48900
-754.500 0.40060 0.44970
-716.500 0.47010 0.39760
-674.800 0.55090 0.33700
-644.300 0.60040 0.29980
-640.000 0.60630 0.29540
-621.100 0.63450 0.27430
-603.300 0.65700 0.25730
-574.000 0.69070 0.23510
-543.300 0.72170 0.20880
-518.300 0.74360 0.19240
-484.400 0.77020 0.17240
-453.900 0.79200 0.15600

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Nagata I.; Tamura K.: Excess Enthalpies of Binary and Ternary Mixtures of Methanol with Acetone, Chloroform, Benzene, and Tetrachloromethane. Fluid Phase Equilib. 15 (1983) 67-79

List of All References

Source
Morris J.W.; Mulvey P.J.; Abbott M.M.; van Ness H.C.: I. Acetone-Chloroform-Methanol at 50 °C. J.Chem.Eng.Data 20 (1975) 403-405
Nagata I.; Tamura K.: Excess Enthalpies of Binary and Ternary Mixtures of Methanol with Acetone, Chloroform, Benzene, and Tetrachloromethane. Fluid Phase Equilib. 15 (1983) 67-79

Excess Enthalpy Data Overview


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