Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 8738

Components

No. Formula Molar Mass CAS Registry Number Name
1 CHCl3 119.377 67-66-3 Chloroform
2 C3H6O 58.080 67-64-1 Acetone
3 C6H6 78.114 71-43-2 Benzene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol] x2 [mol/mol]
13.100 0.01240 0.03760
11.700 0.02480 0.07520
-24.100 0.02490 0.02510
-1.800 0.03720 0.11280
-40.200 0.03750 0.01250
-24.600 0.04950 0.15050
-52.500 0.04990 0.05010
-57.200 0.06190 0.18810
-98.500 0.07430 0.22570
-91.800 0.07480 0.07520
-86.800 0.07490 0.02510
-145.700 0.08670 0.26330
-199.200 0.09910 0.30090
-141.500 0.09970 0.10030
-256.700 0.11150 0.33850
-140.600 0.11240 0.03760
-318.400 0.12380 0.37620
-200.200 0.12470 0.12530
-385.300 0.13620 0.41380
-455.800 0.14860 0.45140
-268.500 0.14960 0.15040
-200.300 0.14980 0.05020
-529.400 0.16100 0.48900
-607.000 0.17340 0.52660
-346.400 0.17450 0.17550
-688.600 0.18580 0.56420
-266.000 0.18730 0.06270
-774.200 0.19810 0.60190
-433.900 0.19940 0.20060
-864.100 0.21050 0.63950
-958.200 0.22290 0.67710
-527.300 0.22440 0.22560
-337.200 0.22470 0.07530
-1057.100 0.23530 0.71410
-623.100 0.24930 0.25070
-414.200 0.26220 0.08780
-723.100 0.27420 0.27580
-833.700 0.29920 0.30080
-496.000 0.29960 0.10040
-950.100 0.32410 0.32590
-580.200 0.33710 0.11290
-1070.200 0.34900 0.35100
-1194.700 0.37400 0.37600
-666.600 0.37450 0.12550
-1324.600 0.39890 0.40110
-755.100 0.41200 0.13800
-1458.500 0.42380 0.42620
-1596.800 0.44870 0.45130
-845.200 0.44940 0.15060
-1740.500 0.47370 0.47630
-937.200 0.48690 0.16310
-1030.100 0.52430 0.18570
-1123.600 0.56180 0.18820
-1217.100 0.59920 0.20080
-1310.100 0.63670 0.21330
-1402.100 0.67410 0.22590
-1491.800 0.71160 0.23840

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Nagata I.; Ozaki S.; Myohen K.: Excess molar enthalpies for (acetonitrile + butan-2-one), (acetonitrile + trichloromethane + butan-2-one), and (trichloromethane + propan-2-one + benzene). J.Chem.Thermodyn. 24 (1992) 607-611


Enthalpy of Mixing Data Set 18220

Components

No. Formula Molar Mass CAS Registry Number Name
1 C3H6O 58.080 67-64-1 Acetone
2 CHCl3 119.377 67-66-3 Chloroform
3 C6H6 78.114 71-43-2 Benzene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [cal/mol] x1 [mol/mol] x2 [mol/mol]
-85.000 0.79900 0.10100
-170.000 0.71800 0.18200
-250.000 0.62700 0.27300
-330.000 0.54500 0.35500
-380.000 0.45000 0.45000
-410.000 0.31400 0.58600
-300.000 0.19000 0.71000
-290.000 0.15100 0.74900
-210.000 0.10600 0.79400

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Campbell A.N.; Kartzmark E.M.; Friesen H.: The Equilibrium Diagrams, Heats of Mixing, Dipole Moments, Densities and Boiling Points of the System Acetone-Chloroform-Benzene. Can.J.Chem. 39 (1961) 735-744


Enthalpy of Mixing Data Set 18221

Components

No. Formula Molar Mass CAS Registry Number Name
1 C3H6O 58.080 67-64-1 Acetone
2 CHCl3 119.377 67-66-3 Chloroform
3 C6H6 78.114 71-43-2 Benzene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [cal/mol] x1 [mol/mol] x2 [mol/mol]
-100.000 0.68100 0.11900
-170.000 0.62000 0.18000
-280.000 0.50600 0.29400
-350.000 0.41500 0.38500
-350.000 0.30200 0.49800
-320.000 0.20100 0.59900
-210.000 0.09500 0.70500

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Campbell A.N.; Kartzmark E.M.; Friesen H.: The Equilibrium Diagrams, Heats of Mixing, Dipole Moments, Densities and Boiling Points of the System Acetone-Chloroform-Benzene. Can.J.Chem. 39 (1961) 735-744

List of All References

Source
Campbell A.N.; Kartzmark E.M.; Friesen H.: The Equilibrium Diagrams, Heats of Mixing, Dipole Moments, Densities and Boiling Points of the System Acetone-Chloroform-Benzene. Can.J.Chem. 39 (1961) 735-744
Nagata I.; Ozaki S.; Myohen K.: Excess molar enthalpies for (acetonitrile + butan-2-one), (acetonitrile + trichloromethane + butan-2-one), and (trichloromethane + propan-2-one + benzene). J.Chem.Thermodyn. 24 (1992) 607-611

Excess Enthalpy Data Overview


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