Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 10280

Components

No. Formula Molar Mass CAS Registry Number Name
1 C2H4O2 60.053 64-19-7 Acetic acid
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-968.000 0.09960
-1895.000 0.20210
-3124.000 0.36320
-3135.000 0.36360
-3461.000 0.42300
-3618.000 0.46980
-3653.000 0.48230
-3660.000 0.48660
-3681.000 0.49800
-3674.000 0.49860
-3667.000 0.52040
-3657.000 0.53400
-3662.000 0.54030
-3560.000 0.57550
-3503.000 0.58900
-2826.000 0.70100
-2016.000 0.79950
-1515.000 0.84970
-529.000 0.95060

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Ryabtseva N.V.; Rudin V.Ya.; Kalinichenko V.P.: Kalorimetrische Untersuchung der Mischungsenthalpie in binären Systemen N-Methylpyrrolidon-Essigsäure und N-Methylpyrrolidon-Wasser. Oniitekhim (1982) 1-8


Enthalpy of Mixing Data Set 10281

Components

No. Formula Molar Mass CAS Registry Number Name
1 C2H4O2 60.053 64-19-7 Acetic acid
2 C5H9NO 99.133 872-50-4 N-Methyl-2-pyrrolidone
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 308.150 K

Data Table

hE [J/mol] x1 [mol/mol]
-1796.000 0.19160
-3444.000 0.42200
-3646.000 0.49010
-3654.000 0.51510
-3645.000 0.53200
-3543.000 0.57710
-3530.000 0.57760
-2026.000 0.79570

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Ryabtseva N.V.; Rudin V.Ya.; Kalinichenko V.P.: Kalorimetrische Untersuchung der Mischungsenthalpie in binären Systemen N-Methylpyrrolidon-Essigsäure und N-Methylpyrrolidon-Wasser. Oniitekhim (1982) 1-8

Diagrams

Excess Enthalpies of Acetic acid+N-Methyl-2-pyrrolidone
See larger image

List of All References

Source
Ryabtseva N.V.; Rudin V.Ya.; Kalinichenko V.P.: Kalorimetrische Untersuchung der Mischungsenthalpie in binären Systemen N-Methylpyrrolidon-Essigsäure und N-Methylpyrrolidon-Wasser. Oniitekhim (1982) 1-8

Excess Enthalpy Data Overview


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