Dortmund Data Bank
Excess Enthalpy Data
The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.
Enthalpy of Mixing Data Set 682
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 2 |
C2H4O2 |
60.053 |
64-19-7 |
Acetic acid |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| 64.600 |
0.07900 |
| 69.100 |
0.08800 |
| 71.600 |
0.16400 |
| 60.700 |
0.19900 |
| 42.500 |
0.25300 |
| 18.300 |
0.30000 |
| -8.400 |
0.34400 |
| -36.500 |
0.40300 |
| -61.900 |
0.44100 |
| -88.400 |
0.50200 |
| -108.000 |
0.54300 |
| -113.000 |
0.55700 |
| -125.000 |
0.60000 |
| -131.000 |
0.65000 |
| -135.000 |
0.70000 |
| -111.000 |
0.80000 |
| -82.900 |
0.86800 |
| -67.500 |
0.89800 |
| -35.100 |
0.95000 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Abramov E.V.; Mirzayan A.S.; Devina O.A.: Bildungswärme der ternären Systeme. 3.. Izv.Akad.Nauk Kaz.SSR Ser.Khim. 23 (1973) 29-34 |
Enthalpy of Mixing Data Set 6521
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 2 |
C2H4O2 |
60.053 |
64-19-7 |
Acetic acid |
Search the DDB for all data of this mixture
Miscibility gap: No
Constant Value
Data Table
| hE [J/mol] |
x1 [mol/mol] |
| 34.370 |
0.05100 |
| 44.400 |
0.13570 |
| 25.510 |
0.19120 |
| 3.850 |
0.24480 |
| -30.980 |
0.30070 |
| -119.800 |
0.41390 |
| -198.480 |
0.52940 |
| -261.590 |
0.64260 |
| -268.710 |
0.69230 |
| -268.460 |
0.73480 |
| -256.440 |
0.80080 |
| -212.440 |
0.86020 |
| -133.180 |
0.91200 |
| -77.830 |
0.94450 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Zhao J.; Bao J.; Hu Y.: Excess molar enthalpies of (an alkanol + a carboxylic acid) at 298.15 K measured with a Picker calorimeter. J.Chem.Thermodyn. 21 (1989) 811-818 |
Diagrams
List of All References
| Source |
| Abramov E.V.; Mirzayan A.S.; Devina O.A.: Bildungswärme der ternären Systeme. 3.. Izv.Akad.Nauk Kaz.SSR Ser.Khim. 23 (1973) 29-34 |
| Zhao J.; Bao J.; Hu Y.: Excess molar enthalpies of (an alkanol + a carboxylic acid) at 298.15 K measured with a Picker calorimeter. J.Chem.Thermodyn. 21 (1989) 811-818 |
Excess Enthalpy Data Overview
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