Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 3288

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C6H12O2 116.160 123-86-4 Acetic acid butyl ester
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Miscibility gap: Yes

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
103.800 0.01050
201.300 0.02040
315.000 0.03460
394.300 0.04440
493.300 0.06050
567.700 0.07190
523.400 0.13700
511.500 0.16190
419.800 0.31350
264.100 0.55830
229.900 0.61400
119.100 0.79450
57.800 0.89110
-2.800 0.99010
-8.100 0.99910
-5.800 0.99940
-3.500 0.99960
-1.800 0.99980

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Richon D.; Viallard A.: I. Étude calorimétrique des systèmes eau/acétate d´alcoyle. Can.J.Chem. 54 (1976) 2584-2593


Enthalpy of Mixing Data Set 7880

Components

No. Formula Molar Mass CAS Registry Number Name
1 H2O 18.015 7732-18-5 Water
2 C6H12O2 116.160 123-86-4 Acetic acid butyl ester
Search the DDB for all data of this mixture

Miscibility gap: Yes

Constant Value

Temperature 298.000 K
Pressure 1.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
509.000 0.06900
552.000 0.11700
554.000 0.20000
523.000 0.29700
455.000 0.40000
390.000 0.49600
315.000 0.59100
230.000 0.70100
89.000 0.88000
73.000 0.90100
34.000 0.95100
20.000 0.97000
5.300 0.99000
-0.400 0.99800

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Bender M.; Heintz A.; Lichtenthaler R.N.: Excess Enthalpy of the System Butyl Acetate + Butan-1-ol + Acetic Acid + Water at 313 K and Ambient Pressure. Thermochim.Acta 187 (1991) 79-94

Diagrams

Excess Enthalpies of Acetic acid butyl ester+Water
See larger image

List of All References

Source
Bender M.; Heintz A.; Lichtenthaler R.N.: Excess Enthalpy of the System Butyl Acetate + Butan-1-ol + Acetic Acid + Water at 313 K and Ambient Pressure. Thermochim.Acta 187 (1991) 79-94
Richon D.; Viallard A.: I. Étude calorimétrique des systèmes eau/acétate d´alcoyle. Can.J.Chem. 54 (1976) 2584-2593

Excess Enthalpy Data Overview


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