Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 6858

Components

No. Formula Molar Mass CAS Registry Number Name
1 CH4O 32.042 67-56-1 Methanol
2 C6H12 84.161 592-41-6 1-Hexene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 5.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
411.662 0.10800
493.102 0.20130
522.574 0.25680
523.989 0.25680
524.148 0.25680
542.836 0.35430
547.066 0.43740
551.438 0.43740
554.271 0.43740
528.419 0.57130
529.853 0.57130
479.830 0.67460
481.911 0.67460
418.731 0.75660
421.794 0.75660
349.790 0.82340
352.325 0.82340
273.018 0.87890
273.984 0.87890
189.892 0.92560
190.539 0.92560
96.957 0.96550
98.078 0.96550
48.263 0.98340

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Gmehling J.; Meents B.: Excess Enthalpies of Some Alkanol (C1 - C4) + Alkane (C5 - C8) or + 1-Alkene (C6, C8) Mixtures. Int.Data Series Sel.Data Mixtures Ser. A 1992 (1992) 153-160


Enthalpy of Mixing Data Set 7025

Components

No. Formula Molar Mass CAS Registry Number Name
1 C6H12 84.161 592-41-6 1-Hexene
2 CH4O 32.042 67-56-1 Methanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 328.180 K
Pressure 5.000 bar

Data Table

hE [J/mol] x1 [mol/mol]
129.716 0.03450
128.860 0.03450
260.986 0.07440
258.044 0.07440
259.983 0.07440
325.159 0.09680
323.118 0.09680
386.197 0.12110
511.755 0.17660
637.046 0.24340
756.393 0.32540
869.183 0.42870
919.639 0.49110
918.117 0.49110
960.221 0.56260
956.078 0.56260
981.890 0.64570
935.458 0.74320
912.083 0.79870
758.749 0.89200
662.971 0.92620
477.654 0.96210
311.847 0.98080

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Gmehling J.; Meents B.: Excess Enthalpies of Some Alkanol (C1 - C4) + Alkane (C5 - C8) or + 1-Alkene (C6, C8) Mixtures. Int.Data Series Sel.Data Mixtures Ser. A 1992 (1992) 153-160


Enthalpy of Mixing Data Set 7027

Components

No. Formula Molar Mass CAS Registry Number Name
1 C6H12 84.161 592-41-6 1-Hexene
2 CH4O 32.042 67-56-1 Methanol
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
123.600 0.04730
274.600 0.12490
363.200 0.19150
442.400 0.27320
497.400 0.34620
529.100 0.41130
553.200 0.48450
570.100 0.56140
573.400 0.66320
530.900 0.76930
480.900 0.81660
285.000 0.92210

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Letcher T.M.; Schoonbaert F.E.Z.; Mercer-Chalmers J.; Prasad A.K.: Excess Enthalpies and Volumes of Binary Mixtures of 1-Alkenes with Methanol and with Ethanol. Thermochim.Acta 171 (1990) 147-152

Diagrams

Excess Enthalpies of 1-Hexene+Methanol
See larger image

List of All References

Source
Gmehling J.; Meents B.: Excess Enthalpies of Some Alkanol (C1 - C4) + Alkane (C5 - C8) or + 1-Alkene (C6, C8) Mixtures. Int.Data Series Sel.Data Mixtures Ser. A 1992 (1992) 153-160
Letcher T.M.; Schoonbaert F.E.Z.; Mercer-Chalmers J.; Prasad A.K.: Excess Enthalpies and Volumes of Binary Mixtures of 1-Alkenes with Methanol and with Ethanol. Thermochim.Acta 171 (1990) 147-152

Excess Enthalpy Data Overview


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