Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 1963

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 71-36-3 1-Butanol
2 C8H10 106.167 106-42-3 p-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K
Pressure 1.700 bar

Data Table

hE [J/mol] x1 [mol/mol]
562.000 0.05940
662.000 0.08050
778.400 0.11960
805.800 0.12790
804.900 0.12920
859.600 0.15780
907.000 0.19160
917.200 0.19530
954.300 0.23200
972.800 0.24820
971.700 0.25130
980.600 0.26810
992.500 0.30340
988.500 0.30990
997.900 0.33800
996.500 0.35120
996.800 0.36140
993.400 0.36220
994.600 0.37200
977.000 0.41550
940.100 0.46760
936.400 0.46810
898.000 0.51590
829.900 0.56470
820.400 0.56900
686.500 0.65460
670.800 0.66450
522.800 0.74440
503.100 0.75490
342.800 0.83270
332.000 0.84070
162.200 0.92240

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Christensen J.J.; Rossiter B.E.; O'Neill T.K.; Hanks R.W.: The Excess Enthalpies of Six p-Xylene + Alcohol Mixtures at 298.15 K. J.Chem.Thermodyn. 10 (1978) 829-833


Enthalpy of Mixing Data Set 4613

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 71-36-3 1-Butanol
2 C8H10 106.167 106-42-3 p-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
676.000 0.08260
810.000 0.13150
904.000 0.18310
940.000 0.21360
973.000 0.24460
985.000 0.26970
1002.000 0.28790
1009.000 0.30830
1009.000 0.32980
1006.000 0.35040
999.000 0.38080
981.000 0.41050
964.000 0.44340
945.000 0.47420
893.000 0.51810
856.000 0.55320
756.000 0.62390
673.000 0.67360
605.000 0.71160
520.000 0.75880
426.000 0.80380

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Rodriguez-Nunez E.; Paz-Andrade M.I.; Jimenez E.; Bravo R.: II. Excess molar enthalpies at 298.15 K for 1-propanol, 1-butanol, and 1-pentanol. J.Chem.Thermodyn. 17 (1985) 23-28


Enthalpy of Mixing Data Set 19410

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 71-36-3 1-Butanol
2 C8H10 106.167 106-42-3 p-Xylene
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 308.150 K

Data Table

hE [J/mol] x1 [mol/mol]
481.400 0.08245
691.000 0.13969
932.400 0.21475
1069.500 0.27949
1105.000 0.32432
1084.600 0.39629
1029.300 0.45448
944.000 0.52031
849.400 0.57592
655.200 0.66415
523.600 0.72432
399.200 0.78917
253.700 0.86947
185.400 0.91273
70.100 0.96310

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Bhardwaj U.; Singh K.C.: Excess molar enthalpies of mixing of 1-butanol with aromatic hydrocarbons at 308.15 K. Indian J.Chem.Sect.A 37 (1998) 1063-1069

Diagrams

Excess Enthalpies of 1-Butanol+p-Xylene
See larger image

List of All References

Source
Bhardwaj U.; Singh K.C.: Excess molar enthalpies of mixing of 1-butanol with aromatic hydrocarbons at 308.15 K. Indian J.Chem.Sect.A 37 (1998) 1063-1069
Christensen J.J.; Rossiter B.E.; O'Neill T.K.; Hanks R.W.: The Excess Enthalpies of Six p-Xylene + Alcohol Mixtures at 298.15 K. J.Chem.Thermodyn. 10 (1978) 829-833
Rodriguez-Nunez E.; Paz-Andrade M.I.; Jimenez E.; Bravo R.: II. Excess molar enthalpies at 298.15 K for 1-propanol, 1-butanol, and 1-pentanol. J.Chem.Thermodyn. 17 (1985) 23-28

Excess Enthalpy Data Overview


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