Dortmund Data Bank
Excess Enthalpy Data
The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.
Enthalpy of Mixing Data Set 4708
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
C4H10O |
74.123 |
71-36-3 |
1-Butanol |
| 2 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 3 |
H2O |
18.015 |
7732-18-5 |
Water |
Search the DDB for all data of this mixture
Miscibility gap: Yes
Constant Value
| Temperature |
293.150 |
K |
| Pressure |
1.010 |
bar |
Data Table
| hE [J/mol] |
x1 [mol/mol] |
x2 [mol/mol] |
| -839.680 |
0.07250 |
0.27590 |
| -612.250 |
0.13760 |
0.25660 |
| -431.060 |
0.19640 |
0.23910 |
| -277.740 |
0.24980 |
0.22320 |
| -159.850 |
0.29850 |
0.20870 |
| 158.610 |
0.48910 |
0.15200 |
| 263.800 |
0.62140 |
0.11260 |
| 301.230 |
0.71850 |
0.08370 |
| 289.620 |
0.79290 |
0.06160 |
| 257.920 |
0.85170 |
0.04410 |
| 215.920 |
0.89940 |
0.02990 |
| 155.020 |
0.93780 |
0.01820 |
| 75.720 |
0.97180 |
0.00840 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Battler J.R.; Rowley R.L.: Excess enthalpies between 293 and 323 K for constituent binaries of ternary mixtures exhibiting partial miscibility. J.Chem.Thermodyn. 17 (1985) 719-732 |
Enthalpy of Mixing Data Set 4709
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
C4H10O |
74.123 |
71-36-3 |
1-Butanol |
| 2 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 3 |
H2O |
18.015 |
7732-18-5 |
Water |
Search the DDB for all data of this mixture
Miscibility gap: Yes
Constant Value
| Temperature |
298.150 |
K |
| Pressure |
1.010 |
bar |
Data Table
| hE [J/mol] |
x1 [mol/mol] |
x2 [mol/mol] |
| -782.910 |
0.07250 |
0.27590 |
| -557.680 |
0.13760 |
0.25660 |
| -353.380 |
0.19640 |
0.23910 |
| -179.760 |
0.24980 |
0.22320 |
| -69.355 |
0.29850 |
0.20870 |
| 244.750 |
0.48910 |
0.15200 |
| 349.440 |
0.62140 |
0.11260 |
| 368.620 |
0.71850 |
0.08370 |
| 353.510 |
0.79290 |
0.06160 |
| 308.750 |
0.85170 |
0.04410 |
| 247.380 |
0.89940 |
0.02990 |
| 178.880 |
0.93780 |
0.01820 |
| 89.120 |
0.97180 |
0.00840 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Battler J.R.; Rowley R.L.: Excess enthalpies between 293 and 323 K for constituent binaries of ternary mixtures exhibiting partial miscibility. J.Chem.Thermodyn. 17 (1985) 719-732 |
Enthalpy of Mixing Data Set 4710
Components
| No. |
Formula |
Molar Mass |
CAS Registry Number |
Name |
| 1 |
C4H10O |
74.123 |
71-36-3 |
1-Butanol |
| 2 |
CH4O |
32.042 |
67-56-1 |
Methanol |
| 3 |
H2O |
18.015 |
7732-18-5 |
Water |
Search the DDB for all data of this mixture
Miscibility gap: Yes
Constant Value
| Temperature |
303.150 |
K |
| Pressure |
1.010 |
bar |
Data Table
| hE [J/mol] |
x1 [mol/mol] |
x2 [mol/mol] |
| -700.100 |
0.07250 |
0.27590 |
| -472.840 |
0.13760 |
0.25660 |
| -280.290 |
0.19640 |
0.23910 |
| -121.010 |
0.24980 |
0.22320 |
| -6.095 |
0.29850 |
0.20870 |
| 323.770 |
0.48910 |
0.15200 |
| 401.240 |
0.62140 |
0.11260 |
| 418.500 |
0.71850 |
0.08370 |
| 389.150 |
0.79290 |
0.06160 |
| 333.070 |
0.85170 |
0.04410 |
| 274.970 |
0.89940 |
0.02990 |
| 189.740 |
0.93780 |
0.01820 |
| 88.460 |
0.97180 |
0.00840 |
(hE - excess enthalpy, x - liquid mole fraction)
Reference
| Source |
| Battler J.R.; Rowley R.L.: Excess enthalpies between 293 and 323 K for constituent binaries of ternary mixtures exhibiting partial miscibility. J.Chem.Thermodyn. 17 (1985) 719-732 |
List of All References
| Source |
| Battler J.R.; Rowley R.L.: Excess enthalpies between 293 and 323 K for constituent binaries of ternary mixtures exhibiting partial miscibility. J.Chem.Thermodyn. 17 (1985) 719-732 |
Excess Enthalpy Data Overview
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