Dortmund Data Bank

Excess Enthalpy Data

The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition. The data represent a small sub list of all available data in the Dortmund Data Bank. For more data or any further information please search the DDB or contact DDBST.


Enthalpy of Mixing Data Set 1943

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 71-36-3 1-Butanol
2 C6H12O2 116.160 123-86-4 Acetic acid butyl ester
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
1066.000 0.19770
1254.000 0.27490
1400.000 0.35890
1428.000 0.37600
1460.000 0.41320
1453.000 0.43640
1459.000 0.46330
1453.000 0.50870
1424.000 0.53330
1388.000 0.58310
1325.000 0.61020
1256.000 0.63900
1224.000 0.66390
1204.000 0.67110
1042.000 0.74680
875.000 0.80490
733.000 0.84610
397.000 0.92480

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Bravo R.; Paz-Andrade M.I.; Kehiaian H.V.: Microcalorimetria de Mezclas Liquidas. Estudio Teorico-Experimental de los Sistemas Ester + Alcohol. Acta Cient.Compostelana 16 (1979) 141-163


Enthalpy of Mixing Data Set 1944

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 71-36-3 1-Butanol
2 C6H12O2 116.160 123-86-4 Acetic acid butyl ester
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 298.150 K

Data Table

hE [J/mol] x1 [mol/mol]
572.000 0.09430
807.000 0.13850
958.000 0.16930
1059.000 0.20350
1131.000 0.22750
1224.000 0.25630
1354.000 0.33380
1378.000 0.36990
1526.000 0.51910
1218.000 0.66910
1134.000 0.69990
1026.000 0.73750
933.000 0.79830
721.000 0.84590
577.000 0.88480
514.000 0.90010

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Kehlen H.; Fuhrmann E.: Die Exzeßenthalpien in Butylacetat-Butanol-Mischungen. Z.Phys.Chem.(Leipzig) 259 (1978) 373-376


Enthalpy of Mixing Data Set 1945

Components

No. Formula Molar Mass CAS Registry Number Name
1 C4H10O 74.123 71-36-3 1-Butanol
2 C6H12O2 116.160 123-86-4 Acetic acid butyl ester
Search the DDB for all data of this mixture

Miscibility gap: No

Constant Value

Temperature 313.150 K

Data Table

hE [J/mol] x1 [mol/mol]
1228.000 0.33200
1362.000 0.46500
1385.000 0.49740
1361.000 0.55080
972.000 0.76420

(hE - excess enthalpy, x - liquid mole fraction)

Reference

Source
Kehlen H.; Fuhrmann E.: Die Exzeßenthalpien in Butylacetat-Butanol-Mischungen. Z.Phys.Chem.(Leipzig) 259 (1978) 373-376

Diagrams

Excess Enthalpies of 1-Butanol+Acetic acid butyl ester
See larger image

List of All References

Source
Kehlen H.; Fuhrmann E.: Die Exzeßenthalpien in Butylacetat-Butanol-Mischungen. Z.Phys.Chem.(Leipzig) 259 (1978) 373-376
Bravo R.; Paz-Andrade M.I.; Kehiaian H.V.: Microcalorimetria de Mezclas Liquidas. Estudio Teorico-Experimental de los Sistemas Ester + Alcohol. Acta Cient.Compostelana 16 (1979) 141-163

Excess Enthalpy Data Overview


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